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Tris(1H-imidazole-κN (3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3) O (2),O (3),O (7))cobalt(II) 3.35-hydrate
In the crystal structure of the title compound, [Co(C(8)H(8)O(5))(C(3)H(4)N(2))(3)]·3.35H(2)O, the central Co(II) ion is in a slightly distorted octahedral environment, coordinated by the bridging O atom from the bicyclo[2.2.1]heptane ligand, by two carboxylate O atoms from two different carboxy...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977092/ https://www.ncbi.nlm.nih.gov/pubmed/21583323 http://dx.doi.org/10.1107/S1600536809024039 |
| _version_ | 1782191024699867136 |
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| author | Wang, Yan-Jun Hu, Rui-Ding Lin, Qiu-Yue Cheng, Jian-Ping |
| author_facet | Wang, Yan-Jun Hu, Rui-Ding Lin, Qiu-Yue Cheng, Jian-Ping |
| author_sort | Wang, Yan-Jun |
| collection | PubMed |
| description | In the crystal structure of the title compound, [Co(C(8)H(8)O(5))(C(3)H(4)N(2))(3)]·3.35H(2)O, the central Co(II) ion is in a slightly distorted octahedral environment, coordinated by the bridging O atom from the bicyclo[2.2.1]heptane ligand, by two carboxylate O atoms from two different carboxylate groups and by three N atoms from imidazole ligands. Uncoordinated water molecules, some of them disordered, are present in the crystal structure. In the crystal structure, molecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen-bonding interactions. |
| format | Text |
| id | pubmed-2977092 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29770922010-12-30 Tris(1H-imidazole-κN (3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3) O (2),O (3),O (7))cobalt(II) 3.35-hydrate Wang, Yan-Jun Hu, Rui-Ding Lin, Qiu-Yue Cheng, Jian-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Co(C(8)H(8)O(5))(C(3)H(4)N(2))(3)]·3.35H(2)O, the central Co(II) ion is in a slightly distorted octahedral environment, coordinated by the bridging O atom from the bicyclo[2.2.1]heptane ligand, by two carboxylate O atoms from two different carboxylate groups and by three N atoms from imidazole ligands. Uncoordinated water molecules, some of them disordered, are present in the crystal structure. In the crystal structure, molecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen-bonding interactions. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977092/ /pubmed/21583323 http://dx.doi.org/10.1107/S1600536809024039 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Yan-Jun Hu, Rui-Ding Lin, Qiu-Yue Cheng, Jian-Ping Tris(1H-imidazole-κN (3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3) O (2),O (3),O (7))cobalt(II) 3.35-hydrate |
| title | Tris(1H-imidazole-κN
(3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))cobalt(II) 3.35-hydrate |
| title_full | Tris(1H-imidazole-κN
(3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))cobalt(II) 3.35-hydrate |
| title_fullStr | Tris(1H-imidazole-κN
(3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))cobalt(II) 3.35-hydrate |
| title_full_unstemmed | Tris(1H-imidazole-κN
(3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))cobalt(II) 3.35-hydrate |
| title_short | Tris(1H-imidazole-κN
(3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
O
(2),O
(3),O
(7))cobalt(II) 3.35-hydrate |
| title_sort | tris(1h-imidazole-κn
(3))(7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato-κ(3)
o
(2),o
(3),o
(7))cobalt(ii) 3.35-hydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977092/ https://www.ncbi.nlm.nih.gov/pubmed/21583323 http://dx.doi.org/10.1107/S1600536809024039 |
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