Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate

In the title compound, C(25)H(25)NO(3), the dihydro­pyran ring adopts a half-chair conformation, whereas the pyrrolidine ring is in a twist conformation. The tolyl group is oriented at an angle of 82.92 (7)° with respect to the napthalene ring system. In the crystal structure, mol­ecules are linked...

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Detalles Bibliográficos
Autores principales: Nirmala, S., Kamala, E. Theboral Sugi, Sudha, L., Kathiravan, S., Raghunathan, R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977094/
https://www.ncbi.nlm.nih.gov/pubmed/21583514
http://dx.doi.org/10.1107/S1600536809024738
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author Nirmala, S.
Kamala, E. Theboral Sugi
Sudha, L.
Kathiravan, S.
Raghunathan, R.
author_facet Nirmala, S.
Kamala, E. Theboral Sugi
Sudha, L.
Kathiravan, S.
Raghunathan, R.
author_sort Nirmala, S.
collection PubMed
description In the title compound, C(25)H(25)NO(3), the dihydro­pyran ring adopts a half-chair conformation, whereas the pyrrolidine ring is in a twist conformation. The tolyl group is oriented at an angle of 82.92 (7)° with respect to the napthalene ring system. In the crystal structure, mol­ecules are linked into centrosymmetric dimers by C—H⋯π inter­actions involving the benzene ring of the tolyl group.
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spelling pubmed-29770942010-12-30 Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate Nirmala, S. Kamala, E. Theboral Sugi Sudha, L. Kathiravan, S. Raghunathan, R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(25)NO(3), the dihydro­pyran ring adopts a half-chair conformation, whereas the pyrrolidine ring is in a twist conformation. The tolyl group is oriented at an angle of 82.92 (7)° with respect to the napthalene ring system. In the crystal structure, mol­ecules are linked into centrosymmetric dimers by C—H⋯π inter­actions involving the benzene ring of the tolyl group. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977094/ /pubmed/21583514 http://dx.doi.org/10.1107/S1600536809024738 Text en © Nirmala et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nirmala, S.
Kamala, E. Theboral Sugi
Sudha, L.
Kathiravan, S.
Raghunathan, R.
Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
title Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
title_full Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
title_fullStr Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
title_full_unstemmed Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
title_short Methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
title_sort methyl 1-methyl-3-p-tolyl-1,2,3,3a,4,11c-hexa­hydro­benzo[f]chromeno[4,3-b]pyrrole-3a-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977094/
https://www.ncbi.nlm.nih.gov/pubmed/21583514
http://dx.doi.org/10.1107/S1600536809024738
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