catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]

In the polymeric title compound, [Cd(C(4)H(2)O(4))(C(19)H(12)N(4)O)(2)](n), the Cd(II) centre is eight-coordinated within an N(4)O(4) donor set derived from two chelating 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol ligands and two asymmetrically chelating carboxyl­ate residues of bridging fu...

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Detalles Bibliográficos
Autores principales: Shi, Li-Ping, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977095/
https://www.ncbi.nlm.nih.gov/pubmed/21583349
http://dx.doi.org/10.1107/S1600536809024246
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author Shi, Li-Ping
Tiekink, Edward R. T.
author_facet Shi, Li-Ping
Tiekink, Edward R. T.
author_sort Shi, Li-Ping
collection PubMed
description In the polymeric title compound, [Cd(C(4)H(2)O(4))(C(19)H(12)N(4)O)(2)](n), the Cd(II) centre is eight-coordinated within an N(4)O(4) donor set derived from two chelating 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol ligands and two asymmetrically chelating carboxyl­ate residues of bridging fumarate dianions. The linear chains are linked into a layer in the ac plane via O—H⋯O(carboxyl­ate) hydrogen bonds. Layers are connected into double layers via N—H⋯O(carboxyl­ate) hydrogen bonds and these stack along the b axis. C—H⋯π inter­actions are also present. Disorder in the ethyl­ene portion of the fumarate was modelled over two positions, the major component having a site-occupancy factor of 0.677 (15).
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spelling pubmed-29770952010-12-30 catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato] Shi, Li-Ping Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title compound, [Cd(C(4)H(2)O(4))(C(19)H(12)N(4)O)(2)](n), the Cd(II) centre is eight-coordinated within an N(4)O(4) donor set derived from two chelating 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol ligands and two asymmetrically chelating carboxyl­ate residues of bridging fumarate dianions. The linear chains are linked into a layer in the ac plane via O—H⋯O(carboxyl­ate) hydrogen bonds. Layers are connected into double layers via N—H⋯O(carboxyl­ate) hydrogen bonds and these stack along the b axis. C—H⋯π inter­actions are also present. Disorder in the ethyl­ene portion of the fumarate was modelled over two positions, the major component having a site-occupancy factor of 0.677 (15). International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977095/ /pubmed/21583349 http://dx.doi.org/10.1107/S1600536809024246 Text en © Shi and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Li-Ping
Tiekink, Edward R. T.
catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]
title catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]
title_full catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]
title_fullStr catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]
title_full_unstemmed catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]
title_short catena-Poly[[bis­[4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(II)]-μ-fumarato]
title_sort catena-poly[[bis­[4-(1h-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol]cadmium(ii)]-μ-fumarato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977095/
https://www.ncbi.nlm.nih.gov/pubmed/21583349
http://dx.doi.org/10.1107/S1600536809024246
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AT tiekinkedwardrt catenapolybis41himidazo45f110phenanthrolin2ylphenolcadmiumiimfumarato

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