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Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate

The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are inter­connected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water mol­ecules by N—H⋯Br and O—H⋯Br bonds, forming...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Terao, Hiromitsu, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977096/
https://www.ncbi.nlm.nih.gov/pubmed/21583396
http://dx.doi.org/10.1107/S160053680902772X
Descripción
Sumario:The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are inter­connected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water mol­ecules by N—H⋯Br and O—H⋯Br bonds, forming a three-dimensional network. N—H⋯O inter­actions are also present. The observed three different Hg—Br distances of 2.5597 (6), 2.6862 (8) and 2.6923 (8) Å in the tetra­bromo­mercurate unit are due to the connection of Br atoms to different numbers of H atoms. The Hg, O and two Br atoms are located on a crystallographic mirror plane. The cation has [Image: see text] symmetry with the center of the C—C bond lying on a crystallographic center of inversion.