Cargando…
Ethylenediammonium tetrabromidomercurate(II) monohydrate
The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetrahedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are interconnected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water molecules by N—H⋯Br and O—H⋯Br bonds, forming...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977096/ https://www.ncbi.nlm.nih.gov/pubmed/21583396 http://dx.doi.org/10.1107/S160053680902772X |
Sumario: | The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetrahedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are interconnected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water molecules by N—H⋯Br and O—H⋯Br bonds, forming a three-dimensional network. N—H⋯O interactions are also present. The observed three different Hg—Br distances of 2.5597 (6), 2.6862 (8) and 2.6923 (8) Å in the tetrabromomercurate unit are due to the connection of Br atoms to different numbers of H atoms. The Hg, O and two Br atoms are located on a crystallographic mirror plane. The cation has [Image: see text] symmetry with the center of the C—C bond lying on a crystallographic center of inversion. |
---|