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Ethylenediammonium tetrabromidomercurate(II) monohydrate
The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetrahedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are interconnected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water molecules by N—H⋯Br and O—H⋯Br bonds, forming...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977096/ https://www.ncbi.nlm.nih.gov/pubmed/21583396 http://dx.doi.org/10.1107/S160053680902772X |
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author | Gowda, B. Thimme Foro, Sabine Terao, Hiromitsu Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Terao, Hiromitsu Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetrahedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are interconnected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water molecules by N—H⋯Br and O—H⋯Br bonds, forming a three-dimensional network. N—H⋯O interactions are also present. The observed three different Hg—Br distances of 2.5597 (6), 2.6862 (8) and 2.6923 (8) Å in the tetrabromomercurate unit are due to the connection of Br atoms to different numbers of H atoms. The Hg, O and two Br atoms are located on a crystallographic mirror plane. The cation has [Image: see text] symmetry with the center of the C—C bond lying on a crystallographic center of inversion. |
format | Text |
id | pubmed-2977096 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29770962010-12-30 Ethylenediammonium tetrabromidomercurate(II) monohydrate Gowda, B. Thimme Foro, Sabine Terao, Hiromitsu Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetrahedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are interconnected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water molecules by N—H⋯Br and O—H⋯Br bonds, forming a three-dimensional network. N—H⋯O interactions are also present. The observed three different Hg—Br distances of 2.5597 (6), 2.6862 (8) and 2.6923 (8) Å in the tetrabromomercurate unit are due to the connection of Br atoms to different numbers of H atoms. The Hg, O and two Br atoms are located on a crystallographic mirror plane. The cation has [Image: see text] symmetry with the center of the C—C bond lying on a crystallographic center of inversion. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977096/ /pubmed/21583396 http://dx.doi.org/10.1107/S160053680902772X Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gowda, B. Thimme Foro, Sabine Terao, Hiromitsu Fuess, Hartmut Ethylenediammonium tetrabromidomercurate(II) monohydrate |
title | Ethylenediammonium tetrabromidomercurate(II) monohydrate |
title_full | Ethylenediammonium tetrabromidomercurate(II) monohydrate |
title_fullStr | Ethylenediammonium tetrabromidomercurate(II) monohydrate |
title_full_unstemmed | Ethylenediammonium tetrabromidomercurate(II) monohydrate |
title_short | Ethylenediammonium tetrabromidomercurate(II) monohydrate |
title_sort | ethylenediammonium tetrabromidomercurate(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977096/ https://www.ncbi.nlm.nih.gov/pubmed/21583396 http://dx.doi.org/10.1107/S160053680902772X |
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