Cargando…

Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate

The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are inter­connected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water mol­ecules by N—H⋯Br and O—H⋯Br bonds, forming...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Terao, Hiromitsu, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977096/
https://www.ncbi.nlm.nih.gov/pubmed/21583396
http://dx.doi.org/10.1107/S160053680902772X
_version_ 1782191025651974144
author Gowda, B. Thimme
Foro, Sabine
Terao, Hiromitsu
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Terao, Hiromitsu
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are inter­connected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water mol­ecules by N—H⋯Br and O—H⋯Br bonds, forming a three-dimensional network. N—H⋯O inter­actions are also present. The observed three different Hg—Br distances of 2.5597 (6), 2.6862 (8) and 2.6923 (8) Å in the tetra­bromo­mercurate unit are due to the connection of Br atoms to different numbers of H atoms. The Hg, O and two Br atoms are located on a crystallographic mirror plane. The cation has [Image: see text] symmetry with the center of the C—C bond lying on a crystallographic center of inversion.
format Text
id pubmed-2977096
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29770962010-12-30 Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate Gowda, B. Thimme Foro, Sabine Terao, Hiromitsu Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg(II) atoms in the crystal structure of the title compound, (C(2)H(10)N(2))[HgBr(4)]·H(2)O, are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) ions are inter­connected to the [NH(3)—CH(2)—CH(2)—NH(3)](2+) ions and water mol­ecules by N—H⋯Br and O—H⋯Br bonds, forming a three-dimensional network. N—H⋯O inter­actions are also present. The observed three different Hg—Br distances of 2.5597 (6), 2.6862 (8) and 2.6923 (8) Å in the tetra­bromo­mercurate unit are due to the connection of Br atoms to different numbers of H atoms. The Hg, O and two Br atoms are located on a crystallographic mirror plane. The cation has [Image: see text] symmetry with the center of the C—C bond lying on a crystallographic center of inversion. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977096/ /pubmed/21583396 http://dx.doi.org/10.1107/S160053680902772X Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Terao, Hiromitsu
Fuess, Hartmut
Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate
title Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate
title_full Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate
title_fullStr Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate
title_full_unstemmed Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate
title_short Ethyl­enediammonium tetra­bromido­mercurate(II) monohydrate
title_sort ethyl­enediammonium tetra­bromido­mercurate(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977096/
https://www.ncbi.nlm.nih.gov/pubmed/21583396
http://dx.doi.org/10.1107/S160053680902772X
work_keys_str_mv AT gowdabthimme ethylenediammoniumtetrabromidomercurateiimonohydrate
AT forosabine ethylenediammoniumtetrabromidomercurateiimonohydrate
AT teraohiromitsu ethylenediammoniumtetrabromidomercurateiimonohydrate
AT fuesshartmut ethylenediammoniumtetrabromidomercurateiimonohydrate