Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate

The title compound, [Au(2)(C(26)H(24)P(2))(2)](CF(3)SO(3))(2)·2CH(3)CN, comprises a cyclic cation with a short intra­molecular aurophilic inter­action of 2.9220 (3) Å. The trifluoro­methane­sulfonate anions and acetonitrile solvent mol­ecules are located in channels formed by the complex cations tha...

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Detalles Bibliográficos
Autores principales: Strasser, Christoph E., Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977105/
https://www.ncbi.nlm.nih.gov/pubmed/21583372
http://dx.doi.org/10.1107/S1600536809025513
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author Strasser, Christoph E.
Cronje, Stephanie
Raubenheimer, Helgard G.
author_facet Strasser, Christoph E.
Cronje, Stephanie
Raubenheimer, Helgard G.
author_sort Strasser, Christoph E.
collection PubMed
description The title compound, [Au(2)(C(26)H(24)P(2))(2)](CF(3)SO(3))(2)·2CH(3)CN, comprises a cyclic cation with a short intra­molecular aurophilic inter­action of 2.9220 (3) Å. The trifluoro­methane­sulfonate anions and acetonitrile solvent mol­ecules are located in channels formed by the complex cations that run along the crystallographic c axis. Each counter-anion is also engaged in a C—H⋯O contact with one of the methyl­ene H atoms of a 1,2-bis­(diphenyl­phosphino)ethane (dppe) ligand; another C—H⋯O contact involving an aromatic H atom is also observed.
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spelling pubmed-29771052010-12-30 Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate Strasser, Christoph E. Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(2)(C(26)H(24)P(2))(2)](CF(3)SO(3))(2)·2CH(3)CN, comprises a cyclic cation with a short intra­molecular aurophilic inter­action of 2.9220 (3) Å. The trifluoro­methane­sulfonate anions and acetonitrile solvent mol­ecules are located in channels formed by the complex cations that run along the crystallographic c axis. Each counter-anion is also engaged in a C—H⋯O contact with one of the methyl­ene H atoms of a 1,2-bis­(diphenyl­phosphino)ethane (dppe) ligand; another C—H⋯O contact involving an aromatic H atom is also observed. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977105/ /pubmed/21583372 http://dx.doi.org/10.1107/S1600536809025513 Text en © Strasser et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Strasser, Christoph E.
Cronje, Stephanie
Raubenheimer, Helgard G.
Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
title Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
title_full Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
title_fullStr Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
title_full_unstemmed Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
title_short Bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) P:P′]digold(I)(Au—Au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
title_sort bis[μ-1,2-bis­(diphenyl­phosphino)ethane-κ(2) p:p′]digold(i)(au—au) bis­(trifluoro­methane­sulfonate) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977105/
https://www.ncbi.nlm.nih.gov/pubmed/21583372
http://dx.doi.org/10.1107/S1600536809025513
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AT raubenheimerhelgardg bism12bisdiphenylphosphinoethanek2ppdigoldiauaubistrifluoromethanesulfonateacetonitriledisolvate

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