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Bis(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2) N (3),N (3′))bis(nitrato-κO)lead(II) dihydrate
In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N′-chelated by two 2,2′-diamino-4,4′-bi-1,3-thiazole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octahedral geometry. One of the uncoordinated water molecule...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977107/ https://www.ncbi.nlm.nih.gov/pubmed/21583303 http://dx.doi.org/10.1107/S1600536809029638 |
Sumario: | In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N′-chelated by two 2,2′-diamino-4,4′-bi-1,3-thiazole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octahedral geometry. One of the uncoordinated water molecules is close to an inversion center and is disordered equally over two sites. Intramolecular N—H⋯N and N—H⋯O interactions are present. An extensive hydrogen-bonding network of types N—H⋯O, O—H⋯O, O—H⋯N and O—H⋯S consolidates the crystal structure. |
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