[1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)

The Zn(II) atom in the title compound, [Zn(C(14)H(11)N(3)O(2)S)(C(12)H(8)N(2))]·0.5C(10)H(8)N(2), is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr­oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyrid...

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Detalles Bibliográficos
Autores principales: Tan, Kong Wai, Ng, Chew Hee, Maah, Mohd Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977112/
https://www.ncbi.nlm.nih.gov/pubmed/21583376
http://dx.doi.org/10.1107/S1600536809026245
Descripción
Sumario:The Zn(II) atom in the title compound, [Zn(C(14)H(11)N(3)O(2)S)(C(12)H(8)N(2))]·0.5C(10)H(8)N(2), is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr­oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supra­molecular trimeric unit.

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