[1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)

The Zn(II) atom in the title compound, [Zn(C(14)H(11)N(3)O(2)S)(C(12)H(8)N(2))]·0.5C(10)H(8)N(2), is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr­oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyrid...

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Detalles Bibliográficos
Autores principales: Tan, Kong Wai, Ng, Chew Hee, Maah, Mohd Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977112/
https://www.ncbi.nlm.nih.gov/pubmed/21583376
http://dx.doi.org/10.1107/S1600536809026245
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author Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
author_facet Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
author_sort Tan, Kong Wai
collection PubMed
description The Zn(II) atom in the title compound, [Zn(C(14)H(11)N(3)O(2)S)(C(12)H(8)N(2))]·0.5C(10)H(8)N(2), is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr­oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supra­molecular trimeric unit.
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spelling pubmed-29771122010-12-30 [1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1) Tan, Kong Wai Ng, Chew Hee Maah, Mohd Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(14)H(11)N(3)O(2)S)(C(12)H(8)N(2))]·0.5C(10)H(8)N(2), is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydr­oxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supra­molecular trimeric unit. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977112/ /pubmed/21583376 http://dx.doi.org/10.1107/S1600536809026245 Text en © Tan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Kong Wai
Ng, Chew Hee
Maah, Mohd Jamil
Ng, Seik Weng
[1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)
title [1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)
title_full [1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)
title_fullStr [1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)
title_full_unstemmed [1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)
title_short [1-(4-Hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) N,O,S](1,10-phenanthroline-κ(2) N,N′)zinc(II)–4,4′-bipyridine (2/1)
title_sort [1-(4-hydr­oxy-2-oxidobenzyl­idene)-4-phenyl­thio­semicarbazonato-κ(3) n,o,s](1,10-phenanthroline-κ(2) n,n′)zinc(ii)–4,4′-bipyridine (2/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977112/
https://www.ncbi.nlm.nih.gov/pubmed/21583376
http://dx.doi.org/10.1107/S1600536809026245
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AT maahmohdjamil 14hydroxy2oxidobenzylidene4phenylthiosemicarbazonatok3nos110phenanthrolinek2nnzincii44bipyridine21
AT ngseikweng 14hydroxy2oxidobenzylidene4phenylthiosemicarbazonatok3nos110phenanthrolinek2nnzincii44bipyridine21

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