Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate

The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl­thio­urea (dmtu) and triphenyl­phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra­hedral environment formed by two P atoms from triphenyl­p...

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Detalles Bibliográficos
Autores principales: La-o, Latipah, Pakawatchai, Chaveng, Saithong, Saowanit, Skelton, Brian W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977114/
https://www.ncbi.nlm.nih.gov/pubmed/21583381
http://dx.doi.org/10.1107/S1600536809026798
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author La-o, Latipah
Pakawatchai, Chaveng
Saithong, Saowanit
Skelton, Brian W.
author_facet La-o, Latipah
Pakawatchai, Chaveng
Saithong, Saowanit
Skelton, Brian W.
author_sort La-o, Latipah
collection PubMed
description The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl­thio­urea (dmtu) and triphenyl­phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra­hedral environment formed by two P atoms from triphenyl­phosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the mol­ecules exhibit intra- and inter­molecular N—H⋯Cl inter­actions.
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spelling pubmed-29771142010-12-30 Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate La-o, Latipah Pakawatchai, Chaveng Saithong, Saowanit Skelton, Brian W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CuCl(C(3)H(8)N(2)S)(C(18)H(15)P)(2)]·0.5CH(3)CN, was prepared by the reaction of copper(I) chloride with 1,3-dimethyl­thio­urea (dmtu) and triphenyl­phosphine (PPh(3)) in acetonitrile. The Cu(I) atom has a distorted tetra­hedral environment formed by two P atoms from triphenyl­phosphine, one S atom from the dmtu ligand and one Cl atom. In addition, the mol­ecules exhibit intra- and inter­molecular N—H⋯Cl inter­actions. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977114/ /pubmed/21583381 http://dx.doi.org/10.1107/S1600536809026798 Text en © La-o et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
La-o, Latipah
Pakawatchai, Chaveng
Saithong, Saowanit
Skelton, Brian W.
Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate
title Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate
title_full Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate
title_fullStr Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate
title_full_unstemmed Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate
title_short Chlorido(1,3-dimethyl­thio­urea-κS)bis­(triphenyl­phosphine-κP)copper(I) acetonitrile hemisolvate
title_sort chlorido(1,3-dimethyl­thio­urea-κs)bis­(triphenyl­phosphine-κp)copper(i) acetonitrile hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977114/
https://www.ncbi.nlm.nih.gov/pubmed/21583381
http://dx.doi.org/10.1107/S1600536809026798
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AT saithongsaowanit chlorido13dimethylthioureaksbistriphenylphosphinekpcopperiacetonitrilehemisolvate
AT skeltonbrianw chlorido13dimethylthioureaksbistriphenylphosphinekpcopperiacetonitrilehemisolvate

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