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Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate]
The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxylate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water molecule. The Er(III) atom is co...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977120/ https://www.ncbi.nlm.nih.gov/pubmed/21583314 http://dx.doi.org/10.1107/S1600536809029742 |
Sumario: | The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxylate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water molecule. The Er(III) atom is coordinated by two O atoms and two N atoms from two pyc ligands, one O atom from a third pyc ligand and four O atoms from two oxalate ligands in a distorted monocapped square-antiprismatic geometry. The Ag(I) atom is coordinated by two N atoms from two pyc ligands, one O atom from a third pyc ligand and one O atom from one oxalate ligand. The crystal structure exhibits a three-dimensional heterometallic polymeric network. O—H⋯O hydrogen bonding between the uncoordinated water molecule and carboxylate O atoms is observed. |
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