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Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]

The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxyl­ate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water mol­ecule. The Er(III) atom is co...

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Detalles Bibliográficos
Autores principales: Zhao, Ling-Zhi, He, Rui-Xia, Zhong, Qiu-Gui, Zeng, Rong-Hua, Lu, Dong-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977120/
https://www.ncbi.nlm.nih.gov/pubmed/21583314
http://dx.doi.org/10.1107/S1600536809029742
Descripción
Sumario:The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxyl­ate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water mol­ecule. The Er(III) atom is coordinated by two O atoms and two N atoms from two pyc ligands, one O atom from a third pyc ligand and four O atoms from two oxalate ligands in a distorted monocapped square-anti­prismatic geometry. The Ag(I) atom is coordinated by two N atoms from two pyc ligands, one O atom from a third pyc ligand and one O atom from one oxalate ligand. The crystal structure exhibits a three-dimensional heterometallic polymeric network. O—H⋯O hydrogen bonding between the uncoordinated water mol­ecule and carboxyl­ate O atoms is observed.