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Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate]
The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxylate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water molecule. The Er(III) atom is co...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977120/ https://www.ncbi.nlm.nih.gov/pubmed/21583314 http://dx.doi.org/10.1107/S1600536809029742 |
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author | Zhao, Ling-Zhi He, Rui-Xia Zhong, Qiu-Gui Zeng, Rong-Hua Lu, Dong-Sheng |
author_facet | Zhao, Ling-Zhi He, Rui-Xia Zhong, Qiu-Gui Zeng, Rong-Hua Lu, Dong-Sheng |
author_sort | Zhao, Ling-Zhi |
collection | PubMed |
description | The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxylate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water molecule. The Er(III) atom is coordinated by two O atoms and two N atoms from two pyc ligands, one O atom from a third pyc ligand and four O atoms from two oxalate ligands in a distorted monocapped square-antiprismatic geometry. The Ag(I) atom is coordinated by two N atoms from two pyc ligands, one O atom from a third pyc ligand and one O atom from one oxalate ligand. The crystal structure exhibits a three-dimensional heterometallic polymeric network. O—H⋯O hydrogen bonding between the uncoordinated water molecule and carboxylate O atoms is observed. |
format | Text |
id | pubmed-2977120 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771202010-12-30 Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] Zhao, Ling-Zhi He, Rui-Xia Zhong, Qiu-Gui Zeng, Rong-Hua Lu, Dong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxylate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water molecule. The Er(III) atom is coordinated by two O atoms and two N atoms from two pyc ligands, one O atom from a third pyc ligand and four O atoms from two oxalate ligands in a distorted monocapped square-antiprismatic geometry. The Ag(I) atom is coordinated by two N atoms from two pyc ligands, one O atom from a third pyc ligand and one O atom from one oxalate ligand. The crystal structure exhibits a three-dimensional heterometallic polymeric network. O—H⋯O hydrogen bonding between the uncoordinated water molecule and carboxylate O atoms is observed. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977120/ /pubmed/21583314 http://dx.doi.org/10.1107/S1600536809029742 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Ling-Zhi He, Rui-Xia Zhong, Qiu-Gui Zeng, Rong-Hua Lu, Dong-Sheng Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] |
title | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] |
title_full | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] |
title_fullStr | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] |
title_full_unstemmed | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] |
title_short | Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(III)silver(I)] monohydrate] |
title_sort | poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis(μ(3)-pyrazine-2-carboxylato)erbium(iii)silver(i)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977120/ https://www.ncbi.nlm.nih.gov/pubmed/21583314 http://dx.doi.org/10.1107/S1600536809029742 |
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