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Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]

The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxyl­ate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water mol­ecule. The Er(III) atom is co...

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Autores principales: Zhao, Ling-Zhi, He, Rui-Xia, Zhong, Qiu-Gui, Zeng, Rong-Hua, Lu, Dong-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977120/
https://www.ncbi.nlm.nih.gov/pubmed/21583314
http://dx.doi.org/10.1107/S1600536809029742
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author Zhao, Ling-Zhi
He, Rui-Xia
Zhong, Qiu-Gui
Zeng, Rong-Hua
Lu, Dong-Sheng
author_facet Zhao, Ling-Zhi
He, Rui-Xia
Zhong, Qiu-Gui
Zeng, Rong-Hua
Lu, Dong-Sheng
author_sort Zhao, Ling-Zhi
collection PubMed
description The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxyl­ate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water mol­ecule. The Er(III) atom is coordinated by two O atoms and two N atoms from two pyc ligands, one O atom from a third pyc ligand and four O atoms from two oxalate ligands in a distorted monocapped square-anti­prismatic geometry. The Ag(I) atom is coordinated by two N atoms from two pyc ligands, one O atom from a third pyc ligand and one O atom from one oxalate ligand. The crystal structure exhibits a three-dimensional heterometallic polymeric network. O—H⋯O hydrogen bonding between the uncoordinated water mol­ecule and carboxyl­ate O atoms is observed.
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spelling pubmed-29771202010-12-30 Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate] Zhao, Ling-Zhi He, Rui-Xia Zhong, Qiu-Gui Zeng, Rong-Hua Lu, Dong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, {[AgEr(C(5)H(3)N(2)O(2))(2)(C(2)O(4))]·H(2)O}(n), contains one Er(III) atom, one Ag(I) atom, two pyrazine-2-carboxyl­ate (pyc) ligands, two half oxalate ligands (each lying on an inversion center) and one uncoordinated water mol­ecule. The Er(III) atom is coordinated by two O atoms and two N atoms from two pyc ligands, one O atom from a third pyc ligand and four O atoms from two oxalate ligands in a distorted monocapped square-anti­prismatic geometry. The Ag(I) atom is coordinated by two N atoms from two pyc ligands, one O atom from a third pyc ligand and one O atom from one oxalate ligand. The crystal structure exhibits a three-dimensional heterometallic polymeric network. O—H⋯O hydrogen bonding between the uncoordinated water mol­ecule and carboxyl­ate O atoms is observed. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977120/ /pubmed/21583314 http://dx.doi.org/10.1107/S1600536809029742 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Ling-Zhi
He, Rui-Xia
Zhong, Qiu-Gui
Zeng, Rong-Hua
Lu, Dong-Sheng
Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]
title Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]
title_full Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]
title_fullStr Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]
title_full_unstemmed Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]
title_short Poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(III)silver(I)] monohydrate]
title_sort poly[[hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-bis­(μ(3)-pyrazine-2-carboxyl­ato)erbium(iii)silver(i)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977120/
https://www.ncbi.nlm.nih.gov/pubmed/21583314
http://dx.doi.org/10.1107/S1600536809029742
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