t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one

In the title mol­ecule, C(21)H(24)N(2)O(4), the piperidine ring adopts a distorted boat conformation with the ethyl substituent in the axial position. The dihedral angle between the two benzene rings is 70.25 (9)°. An intra­molecular C—H⋯O inter­action is observed. In the crystal, mol­ecules are lin...

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Autores principales: Kavitha, T., Thenmozhi, M., Ponnuswamy, S., Sakthivel, P., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977124/
https://www.ncbi.nlm.nih.gov/pubmed/21583475
http://dx.doi.org/10.1107/S1600536809024878
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author Kavitha, T.
Thenmozhi, M.
Ponnuswamy, S.
Sakthivel, P.
Ponnuswamy, M. N.
author_facet Kavitha, T.
Thenmozhi, M.
Ponnuswamy, S.
Sakthivel, P.
Ponnuswamy, M. N.
author_sort Kavitha, T.
collection PubMed
description In the title mol­ecule, C(21)H(24)N(2)O(4), the piperidine ring adopts a distorted boat conformation with the ethyl substituent in the axial position. The dihedral angle between the two benzene rings is 70.25 (9)°. An intra­molecular C—H⋯O inter­action is observed. In the crystal, mol­ecules are linked into a chain along the c axis by C—H⋯O hydrogen bonds and the chains are linked via weak C—H⋯π inter­actions.
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spelling pubmed-29771242010-12-30 t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one Kavitha, T. Thenmozhi, M. Ponnuswamy, S. Sakthivel, P. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(21)H(24)N(2)O(4), the piperidine ring adopts a distorted boat conformation with the ethyl substituent in the axial position. The dihedral angle between the two benzene rings is 70.25 (9)°. An intra­molecular C—H⋯O inter­action is observed. In the crystal, mol­ecules are linked into a chain along the c axis by C—H⋯O hydrogen bonds and the chains are linked via weak C—H⋯π inter­actions. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977124/ /pubmed/21583475 http://dx.doi.org/10.1107/S1600536809024878 Text en © Kavitha et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kavitha, T.
Thenmozhi, M.
Ponnuswamy, S.
Sakthivel, P.
Ponnuswamy, M. N.
t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
title t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
title_full t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
title_fullStr t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
title_full_unstemmed t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
title_short t-3-Ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
title_sort t-3-ethyl-r-2,c-6-bis­(4-methoxy­phen­yl)-1-nitro­sopiperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977124/
https://www.ncbi.nlm.nih.gov/pubmed/21583475
http://dx.doi.org/10.1107/S1600536809024878
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AT sakthivelp t3ethylr2c6bis4methoxyphenyl1nitrosopiperidin4one
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