Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)

In the title complex, [Cu(C(12)H(7)Cl(2)N(2)O)(2)], the Cu(II) center is tetra­coordinated by two phenolic O and two azomethine N atoms from two bidentate 4-chloro-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coo...

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Autores principales: Ding, Yu-Jie, Tong, Jun-Feng, Dong, Wen-Kui, Sun, Yin-Xia, Yao, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977127/
https://www.ncbi.nlm.nih.gov/pubmed/21583310
http://dx.doi.org/10.1107/S1600536809029651
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author Ding, Yu-Jie
Tong, Jun-Feng
Dong, Wen-Kui
Sun, Yin-Xia
Yao, Jian
author_facet Ding, Yu-Jie
Tong, Jun-Feng
Dong, Wen-Kui
Sun, Yin-Xia
Yao, Jian
author_sort Ding, Yu-Jie
collection PubMed
description In the title complex, [Cu(C(12)H(7)Cl(2)N(2)O)(2)], the Cu(II) center is tetra­coordinated by two phenolic O and two azomethine N atoms from two bidentate 4-chloro-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The dihedral angles between the benzene and pyridyl rings are 54.39 (3) and 80.14 (4)°, indicating that the pyridine ring has a considerably weaker steric hindrance. The packing of the mol­ecule is controlled by C—H⋯π(Ph) inter­actions and short O⋯Cl inter­actions [3.196 (4) Å], linking the mol­ecules into a chain-like structure along the c axis.
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spelling pubmed-29771272010-12-30 Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II) Ding, Yu-Jie Tong, Jun-Feng Dong, Wen-Kui Sun, Yin-Xia Yao, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(12)H(7)Cl(2)N(2)O)(2)], the Cu(II) center is tetra­coordinated by two phenolic O and two azomethine N atoms from two bidentate 4-chloro-2-[(2-chloro-3-pyrid­yl)imino­meth­yl]phenolate (L) ligands. In the crystal structure, the Cu(II) atom has a distorted square-planar coordination environment. The dihedral angles between the benzene and pyridyl rings are 54.39 (3) and 80.14 (4)°, indicating that the pyridine ring has a considerably weaker steric hindrance. The packing of the mol­ecule is controlled by C—H⋯π(Ph) inter­actions and short O⋯Cl inter­actions [3.196 (4) Å], linking the mol­ecules into a chain-like structure along the c axis. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977127/ /pubmed/21583310 http://dx.doi.org/10.1107/S1600536809029651 Text en © Ding et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ding, Yu-Jie
Tong, Jun-Feng
Dong, Wen-Kui
Sun, Yin-Xia
Yao, Jian
Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)
title Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)
title_full Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)
title_fullStr Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)
title_full_unstemmed Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)
title_short Bis{(E)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κN]phenolato-κO}copper(II)
title_sort bis{(e)-4-chloro-2-[(2-chloro-3-pyrid­yl)imino­methyl-κn]phenolato-κo}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977127/
https://www.ncbi.nlm.nih.gov/pubmed/21583310
http://dx.doi.org/10.1107/S1600536809029651
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