trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)

In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo­penta­dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered...

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Detalles Bibliográficos
Autores principales: Wang, Hong, Dong, Gui-Ying, Ma, Zhi-Hong, Liu, Xiao-Huan, Lin, Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977131/
https://www.ncbi.nlm.nih.gov/pubmed/21583357
http://dx.doi.org/10.1107/S1600536809026075
Descripción
Sumario:In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo­penta­dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered rings which are located on centres of inversion. The Ru—Ru distance of 2.7483 (11) Å corresponds to a single bond. The two carbonyl groups in these binuclear complexes are trans-oriented.

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