trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)

In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo­penta­dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered...

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Detalles Bibliográficos
Autores principales: Wang, Hong, Dong, Gui-Ying, Ma, Zhi-Hong, Liu, Xiao-Huan, Lin, Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977131/
https://www.ncbi.nlm.nih.gov/pubmed/21583357
http://dx.doi.org/10.1107/S1600536809026075
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author Wang, Hong
Dong, Gui-Ying
Ma, Zhi-Hong
Liu, Xiao-Huan
Lin, Jin
author_facet Wang, Hong
Dong, Gui-Ying
Ma, Zhi-Hong
Liu, Xiao-Huan
Lin, Jin
author_sort Wang, Hong
collection PubMed
description In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo­penta­dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered rings which are located on centres of inversion. The Ru—Ru distance of 2.7483 (11) Å corresponds to a single bond. The two carbonyl groups in these binuclear complexes are trans-oriented.
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spelling pubmed-29771312010-12-30 trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru) Wang, Hong Dong, Gui-Ying Ma, Zhi-Hong Liu, Xiao-Huan Lin, Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Ru(2)(C(14)H(17)O)(2)(CO)(4)], each Ru(I) atom is connected to one end-on and two bridging carbonyl groups and one cyclo­penta­dienyl ring. The two Ru atoms are connected into binuclear complexes via two bridging carbonyl groups, forming four-membered rings which are located on centres of inversion. The Ru—Ru distance of 2.7483 (11) Å corresponds to a single bond. The two carbonyl groups in these binuclear complexes are trans-oriented. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977131/ /pubmed/21583357 http://dx.doi.org/10.1107/S1600536809026075 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hong
Dong, Gui-Ying
Ma, Zhi-Hong
Liu, Xiao-Huan
Lin, Jin
trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_full trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_fullStr trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_full_unstemmed trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_short trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_sort trans-di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(5-methyl-2-fur­yl)cyclo­penta­dien­yl]ruthenium(i)}(ru—ru)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977131/
https://www.ncbi.nlm.nih.gov/pubmed/21583357
http://dx.doi.org/10.1107/S1600536809026075
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