7-Bromo-1-methyl­sulfinyl-2-phenyl­naphtho[2,1-b]furan

In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2 (1)°. The crystal structure is stabilize...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977132/
https://www.ncbi.nlm.nih.gov/pubmed/21583634
http://dx.doi.org/10.1107/S1600536809028165
Descripción
Sumario:In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2 (1)°. The crystal structure is stabilized by two inter­molecular C—H⋯π inter­actions, and by non-classical inter­molecular C—H⋯O and C—H⋯Br hydrogen bonds.

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