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7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan
In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2 (1)°. The crystal structure is stabilize...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977132/ https://www.ncbi.nlm.nih.gov/pubmed/21583634 http://dx.doi.org/10.1107/S1600536809028165 |
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author | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2 (1)°. The crystal structure is stabilized by two intermolecular C—H⋯π interactions, and by non-classical intermolecular C—H⋯O and C—H⋯Br hydrogen bonds. |
format | Text |
id | pubmed-2977132 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771322010-12-30 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(13)BrO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the naphthofuran unit. The phenyl ring is rotated out of the naphthofuran plane, making a dihedral angle of 42.2 (1)°. The crystal structure is stabilized by two intermolecular C—H⋯π interactions, and by non-classical intermolecular C—H⋯O and C—H⋯Br hydrogen bonds. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977132/ /pubmed/21583634 http://dx.doi.org/10.1107/S1600536809028165 Text en © Choi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
title | 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
title_full | 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
title_fullStr | 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
title_full_unstemmed | 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
title_short | 7-Bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
title_sort | 7-bromo-1-methylsulfinyl-2-phenylnaphtho[2,1-b]furan |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977132/ https://www.ncbi.nlm.nih.gov/pubmed/21583634 http://dx.doi.org/10.1107/S1600536809028165 |
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