Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)

In the title complex, [Co(NCS)(2)(C(13)H(11)N(3)O)(2)], the Co(II) centre adopts a distorted octa­hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio­cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The Co(II) atom lies on...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Chuang, Nien-Tsu, Huang, Jui-Hsien, Lee, Hon Man
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977133/
https://www.ncbi.nlm.nih.gov/pubmed/21583435
http://dx.doi.org/10.1107/S1600536809029006
Descripción
Sumario:In the title complex, [Co(NCS)(2)(C(13)H(11)N(3)O)(2)], the Co(II) centre adopts a distorted octa­hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio­cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The Co(II) atom lies on a crystallographic twofold rotational axis. Non-classical inter­molecular C—H⋯O hydrogen bonds link the complex mol­ecules into chains along [001].

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