Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)

In the title complex, [Co(NCS)(2)(C(13)H(11)N(3)O)(2)], the Co(II) centre adopts a distorted octa­hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio­cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The Co(II) atom lies on...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Chuang, Nien-Tsu, Huang, Jui-Hsien, Lee, Hon Man
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977133/
https://www.ncbi.nlm.nih.gov/pubmed/21583435
http://dx.doi.org/10.1107/S1600536809029006
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author Datta, Amitabha
Chuang, Nien-Tsu
Huang, Jui-Hsien
Lee, Hon Man
author_facet Datta, Amitabha
Chuang, Nien-Tsu
Huang, Jui-Hsien
Lee, Hon Man
author_sort Datta, Amitabha
collection PubMed
description In the title complex, [Co(NCS)(2)(C(13)H(11)N(3)O)(2)], the Co(II) centre adopts a distorted octa­hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio­cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The Co(II) atom lies on a crystallographic twofold rotational axis. Non-classical inter­molecular C—H⋯O hydrogen bonds link the complex mol­ecules into chains along [001].
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spelling pubmed-29771332010-12-30 Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II) Datta, Amitabha Chuang, Nien-Tsu Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(NCS)(2)(C(13)H(11)N(3)O)(2)], the Co(II) centre adopts a distorted octa­hedral coordination geometry with two cis-bidentate Schiff base ligands and two cis thio­cyanate ligands. The Schiff base ligand coordinates via the imine N and pyridine N atoms. The Co(II) atom lies on a crystallographic twofold rotational axis. Non-classical inter­molecular C—H⋯O hydrogen bonds link the complex mol­ecules into chains along [001]. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977133/ /pubmed/21583435 http://dx.doi.org/10.1107/S1600536809029006 Text en © Datta et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Datta, Amitabha
Chuang, Nien-Tsu
Huang, Jui-Hsien
Lee, Hon Man
Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)
title Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)
title_full Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)
title_short Bis[N′-(2-pyridylmethyl­ene-κN)benzo­hydrazide-κN′]bis­(thio­cyanato-κN)cobalt(II)
title_sort bis[n′-(2-pyridylmethyl­ene-κn)benzo­hydrazide-κn′]bis­(thio­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977133/
https://www.ncbi.nlm.nih.gov/pubmed/21583435
http://dx.doi.org/10.1107/S1600536809029006
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