Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate

In the title compound, C(13)H(13)FO(4)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The crystal structure exhibits four inter­molecular non-classical C—H⋯O hydrogen bonds. In addition, the crystal structure c...

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Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977135/
https://www.ncbi.nlm.nih.gov/pubmed/21583528
http://dx.doi.org/10.1107/S1600536809025938
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author Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_facet Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
author_sort Choi, Hong Dae
collection PubMed
description In the title compound, C(13)H(13)FO(4)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The crystal structure exhibits four inter­molecular non-classical C—H⋯O hydrogen bonds. In addition, the crystal structure contains aromatic π–π inter­actions between the furan and benzene rings of adjacent mol­ecules [centroid–centroid distance = 3.743 (2) Å], and two inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29771352010-12-30 Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate Choi, Hong Dae Seo, Pil Ja Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)FO(4)S, the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The crystal structure exhibits four inter­molecular non-classical C—H⋯O hydrogen bonds. In addition, the crystal structure contains aromatic π–π inter­actions between the furan and benzene rings of adjacent mol­ecules [centroid–centroid distance = 3.743 (2) Å], and two inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977135/ /pubmed/21583528 http://dx.doi.org/10.1107/S1600536809025938 Text en © Choi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Choi, Hong Dae
Seo, Pil Ja
Son, Byeng Wha
Lee, Uk
Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
title Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
title_full Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
title_fullStr Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
title_full_unstemmed Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
title_short Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
title_sort ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977135/
https://www.ncbi.nlm.nih.gov/pubmed/21583528
http://dx.doi.org/10.1107/S1600536809025938
work_keys_str_mv AT choihongdae ethyl25fluoro3methylsulfinyl1benzofuran2ylacetate
AT seopilja ethyl25fluoro3methylsulfinyl1benzofuran2ylacetate
AT sonbyengwha ethyl25fluoro3methylsulfinyl1benzofuran2ylacetate
AT leeuk ethyl25fluoro3methylsulfinyl1benzofuran2ylacetate

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