Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)

The title compound, (C(4)H(12)NO(3))[ReO(4)], contains two cations and two anions in the asymmetric unit, related by a non-crystallographic centre of symmetry. The crystal structure is stabilized by an extensive hydrogen-bonding network with the formation of puckered layers perpendicular to [001]. I...

Descripción completa

Detalles Bibliográficos
Autores principales: Hołyńska, Małgorzata, Lis, Tadeusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977137/
https://www.ncbi.nlm.nih.gov/pubmed/21583437
http://dx.doi.org/10.1107/S1600536809028797
_version_ 1782191035787509760
author Hołyńska, Małgorzata
Lis, Tadeusz
author_facet Hołyńska, Małgorzata
Lis, Tadeusz
author_sort Hołyńska, Małgorzata
collection PubMed
description The title compound, (C(4)H(12)NO(3))[ReO(4)], contains two cations and two anions in the asymmetric unit, related by a non-crystallographic centre of symmetry. The crystal structure is stabilized by an extensive hydrogen-bonding network with the formation of puckered layers perpendicular to [001]. In the tris­(hydroxy­meth­yl)ammonium cations, intra­molecular O—H⋯O hydrogen bonds are present with the formation of an S (1) (1)(6) graph-set motif. The crystal structure is further consolid­ated by N—H⋯O hydrogen bonds.
format Text
id pubmed-2977137
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29771372010-12-30 Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII) Hołyńska, Małgorzata Lis, Tadeusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(4)H(12)NO(3))[ReO(4)], contains two cations and two anions in the asymmetric unit, related by a non-crystallographic centre of symmetry. The crystal structure is stabilized by an extensive hydrogen-bonding network with the formation of puckered layers perpendicular to [001]. In the tris­(hydroxy­meth­yl)ammonium cations, intra­molecular O—H⋯O hydrogen bonds are present with the formation of an S (1) (1)(6) graph-set motif. The crystal structure is further consolid­ated by N—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977137/ /pubmed/21583437 http://dx.doi.org/10.1107/S1600536809028797 Text en © Hołyńska and Lis 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hołyńska, Małgorzata
Lis, Tadeusz
Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)
title Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)
title_full Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)
title_fullStr Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)
title_full_unstemmed Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)
title_short Extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(VII)
title_sort extensive hydrogen-bonding network and an unusual cation conformation in [tris­(hydroxy­meth­yl)methyl]­ammonium tetra­oxidorhenate(vii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977137/
https://www.ncbi.nlm.nih.gov/pubmed/21583437
http://dx.doi.org/10.1107/S1600536809028797
work_keys_str_mv AT hołynskamałgorzata extensivehydrogenbondingnetworkandanunusualcationconformationintrishydroxymethylmethylammoniumtetraoxidorhenatevii
AT listadeusz extensivehydrogenbondingnetworkandanunusualcationconformationintrishydroxymethylmethylammoniumtetraoxidorhenatevii

Ejemplares similares