Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O

During our research into novel nonlinear optical materials using 1,10-phenanthroline as an appending ligand on lanthanide iodates, crystals of an infinite layered Dy(III) iodate compound, Dy(IO(3))(3)(H(2)O)·H(2)O, were obtained under hydro­thermal conditions. The Dy(III) cation has a dicapped trigo...

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Detalles Bibliográficos
Autores principales: Chai, Wenxiang, Song, Li, Shi, Hongsheng, Qin, Laishun, Shu, Kangying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977138/
https://www.ncbi.nlm.nih.gov/pubmed/21583297
http://dx.doi.org/10.1107/S1600536809027068
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author Chai, Wenxiang
Song, Li
Shi, Hongsheng
Qin, Laishun
Shu, Kangying
author_facet Chai, Wenxiang
Song, Li
Shi, Hongsheng
Qin, Laishun
Shu, Kangying
author_sort Chai, Wenxiang
collection PubMed
description During our research into novel nonlinear optical materials using 1,10-phenanthroline as an appending ligand on lanthanide iodates, crystals of an infinite layered Dy(III) iodate compound, Dy(IO(3))(3)(H(2)O)·H(2)O, were obtained under hydro­thermal conditions. The Dy(III) cation has a dicapped trigonal prismatic coordination environment consisting of one water O atom and seven other O atoms from seven iodate anions. These iodate anions bridge the Dy(III) cations into a two-dimensional structure. Through O—H⋯O hydrogen bonds, all of these layers stack along [111], giving a supra­molecular channel, with the solvent water mol­ecules filling the voids.
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spelling pubmed-29771382010-12-30 Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O Chai, Wenxiang Song, Li Shi, Hongsheng Qin, Laishun Shu, Kangying Acta Crystallogr Sect E Struct Rep Online Inorganic Papers During our research into novel nonlinear optical materials using 1,10-phenanthroline as an appending ligand on lanthanide iodates, crystals of an infinite layered Dy(III) iodate compound, Dy(IO(3))(3)(H(2)O)·H(2)O, were obtained under hydro­thermal conditions. The Dy(III) cation has a dicapped trigonal prismatic coordination environment consisting of one water O atom and seven other O atoms from seven iodate anions. These iodate anions bridge the Dy(III) cations into a two-dimensional structure. Through O—H⋯O hydrogen bonds, all of these layers stack along [111], giving a supra­molecular channel, with the solvent water mol­ecules filling the voids. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977138/ /pubmed/21583297 http://dx.doi.org/10.1107/S1600536809027068 Text en © Chai et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Chai, Wenxiang
Song, Li
Shi, Hongsheng
Qin, Laishun
Shu, Kangying
Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O
title Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O
title_full Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O
title_fullStr Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O
title_full_unstemmed Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O
title_short Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O
title_sort two-dimensional dysprosium(iii) triiodate(v) dihydrate, dy(io(3))(3)(h(2)o)·h(2)o
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977138/
https://www.ncbi.nlm.nih.gov/pubmed/21583297
http://dx.doi.org/10.1107/S1600536809027068
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