Bis(creatininium) tetra­chlorido­cadmate(II)

In the title compound, (C(4)H(8)N(3)O)(2)[CdCl(4)], the asymmetric unit comprises two creatininium cations and one tetra­chloridocadmate anion. Cd⋯O secondary bonding links one of the two imidazole rings and the anion into ion pairs. The free and bound cations form layers between which the [CdCl(4)]...

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Autores principales: Boufas, Sihem, Mouas, Toma-Nardjes, Bénard-Rocherullé, Patricia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977141/
https://www.ncbi.nlm.nih.gov/pubmed/21583384
http://dx.doi.org/10.1107/S1600536809026944
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author Boufas, Sihem
Mouas, Toma-Nardjes
Bénard-Rocherullé, Patricia
author_facet Boufas, Sihem
Mouas, Toma-Nardjes
Bénard-Rocherullé, Patricia
author_sort Boufas, Sihem
collection PubMed
description In the title compound, (C(4)H(8)N(3)O)(2)[CdCl(4)], the asymmetric unit comprises two creatininium cations and one tetra­chloridocadmate anion. Cd⋯O secondary bonding links one of the two imidazole rings and the anion into ion pairs. The free and bound cations form layers between which the [CdCl(4)](2−) anions are sandwiched. The Cd(II) atom adopts a distorted trigonal-bipyramidal geometry in which the Cd⋯O bond is axial. Inter­molecular N—H⋯Cl hydrogen bonds form a two-dimensional network parallel to (001) which ensures the junction between creatininium cations and [CdCl(4)](2−) anions.
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spelling pubmed-29771412010-12-30 Bis(creatininium) tetra­chlorido­cadmate(II) Boufas, Sihem Mouas, Toma-Nardjes Bénard-Rocherullé, Patricia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(4)H(8)N(3)O)(2)[CdCl(4)], the asymmetric unit comprises two creatininium cations and one tetra­chloridocadmate anion. Cd⋯O secondary bonding links one of the two imidazole rings and the anion into ion pairs. The free and bound cations form layers between which the [CdCl(4)](2−) anions are sandwiched. The Cd(II) atom adopts a distorted trigonal-bipyramidal geometry in which the Cd⋯O bond is axial. Inter­molecular N—H⋯Cl hydrogen bonds form a two-dimensional network parallel to (001) which ensures the junction between creatininium cations and [CdCl(4)](2−) anions. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977141/ /pubmed/21583384 http://dx.doi.org/10.1107/S1600536809026944 Text en © Boufas et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boufas, Sihem
Mouas, Toma-Nardjes
Bénard-Rocherullé, Patricia
Bis(creatininium) tetra­chlorido­cadmate(II)
title Bis(creatininium) tetra­chlorido­cadmate(II)
title_full Bis(creatininium) tetra­chlorido­cadmate(II)
title_fullStr Bis(creatininium) tetra­chlorido­cadmate(II)
title_full_unstemmed Bis(creatininium) tetra­chlorido­cadmate(II)
title_short Bis(creatininium) tetra­chlorido­cadmate(II)
title_sort bis(creatininium) tetra­chlorido­cadmate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977141/
https://www.ncbi.nlm.nih.gov/pubmed/21583384
http://dx.doi.org/10.1107/S1600536809026944
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AT mouastomanardjes biscreatininiumtetrachloridocadmateii
AT benardrocherullepatricia biscreatininiumtetrachloridocadmateii

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