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(Acetylacetonato-κ(2) O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2) O,N′]manganese(III)
In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion, by...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977142/ https://www.ncbi.nlm.nih.gov/pubmed/21583428 http://dx.doi.org/10.1107/S1600536809028177 |
| _version_ | 1782191036948283392 |
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| author | Xiao, Zi-Jing |
| author_facet | Xiao, Zi-Jing |
| author_sort | Xiao, Zi-Jing |
| collection | PubMed |
| description | In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion, by two O atoms of the acetylacetonate anion and by the O atom of a coordinated water molecule. In the crystal structure, complex molecules are linked into centrosymmetric dimeric units through four intermolecular O—H⋯O hydrogen bonds involving both H atoms of the coordinated water molecule. |
| format | Text |
| id | pubmed-2977142 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29771422010-12-30 (Acetylacetonato-κ(2) O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2) O,N′]manganese(III) Xiao, Zi-Jing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(15)H(11)N(3)O(5))(C(5)H(7)O(2))(H(2)O)], the Mn(III) ion has a distorted octahedral coordination geometry. It is coordinated by a phenoxy O atom, a hydrazine N atom and a carbonyl O atom of the 2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidate dianion, by two O atoms of the acetylacetonate anion and by the O atom of a coordinated water molecule. In the crystal structure, complex molecules are linked into centrosymmetric dimeric units through four intermolecular O—H⋯O hydrogen bonds involving both H atoms of the coordinated water molecule. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977142/ /pubmed/21583428 http://dx.doi.org/10.1107/S1600536809028177 Text en © Zi-Jing Xiao 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xiao, Zi-Jing (Acetylacetonato-κ(2) O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2) O,N′]manganese(III) |
| title | (Acetylacetonato-κ(2)
O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2)
O,N′]manganese(III) |
| title_full | (Acetylacetonato-κ(2)
O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2)
O,N′]manganese(III) |
| title_fullStr | (Acetylacetonato-κ(2)
O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2)
O,N′]manganese(III) |
| title_full_unstemmed | (Acetylacetonato-κ(2)
O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2)
O,N′]manganese(III) |
| title_short | (Acetylacetonato-κ(2)
O,O′)aqua[2-(2-nitrophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ(2)
O,N′]manganese(III) |
| title_sort | (acetylacetonato-κ(2)
o,o′)aqua[2-(2-nitrophenoxy)-n′-(2-oxidobenzylidene-κo)acetohydrazidato-κ(2)
o,n′]manganese(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977142/ https://www.ncbi.nlm.nih.gov/pubmed/21583428 http://dx.doi.org/10.1107/S1600536809028177 |
| work_keys_str_mv | AT xiaozijing acetylacetonatok2ooaqua22nitrophenoxyn2oxidobenzylidenekoacetohydrazidatok2onmanganeseiii |