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catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]

In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]AsF(6)}(n), the Ag(I) ion is coordinated by two N atoms from two different pyridyl rings and one N atom from one carbonitrile group of three different N′-(4-cyano­benzyl­idene)nicotinohydrazide ligands in a distorted T-shaped geometry. The Ag—N(carboni...

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Autores principales: Niu, Cao-Yuan, Ning, Ai-Min, Kou, Chun-Hong, He, Yong, Fen, Zhi-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977146/
https://www.ncbi.nlm.nih.gov/pubmed/21583380
http://dx.doi.org/10.1107/S1600536809026907
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author Niu, Cao-Yuan
Ning, Ai-Min
Kou, Chun-Hong
He, Yong
Fen, Zhi-Qiang
author_facet Niu, Cao-Yuan
Ning, Ai-Min
Kou, Chun-Hong
He, Yong
Fen, Zhi-Qiang
author_sort Niu, Cao-Yuan
collection PubMed
description In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]AsF(6)}(n), the Ag(I) ion is coordinated by two N atoms from two different pyridyl rings and one N atom from one carbonitrile group of three different N′-(4-cyano­benzyl­idene)nicotinohydrazide ligands in a distorted T-shaped geometry. The Ag—N(carbonitrile) bond distance is significant longer than those of Ag—N(pyrid­yl). The bond angles around the Ag(I) atom are also not in line with those in an ideal T-shaped geometry. One type of ligand acts as the bridge that connects Ag(I) atoms into chains along [[Image: see text]01]. These chains are linked to each other via N—H⋯O hydrogen bonds and Ag⋯O inter­actions with an Ag⋯O separation of 2.869 (2) Å. In addition, the [AsF(6)](−) counter-anions are linked to the hydrazone groups through N—H⋯F hydrogen bonds. Four of the F atoms of the [AsF(6)](−) anion are disordered over two sets of sites with occupancies of 0.732 (9) and 0.268 (9).
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spelling pubmed-29771462010-12-30 catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate] Niu, Cao-Yuan Ning, Ai-Min Kou, Chun-Hong He, Yong Fen, Zhi-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]AsF(6)}(n), the Ag(I) ion is coordinated by two N atoms from two different pyridyl rings and one N atom from one carbonitrile group of three different N′-(4-cyano­benzyl­idene)nicotinohydrazide ligands in a distorted T-shaped geometry. The Ag—N(carbonitrile) bond distance is significant longer than those of Ag—N(pyrid­yl). The bond angles around the Ag(I) atom are also not in line with those in an ideal T-shaped geometry. One type of ligand acts as the bridge that connects Ag(I) atoms into chains along [[Image: see text]01]. These chains are linked to each other via N—H⋯O hydrogen bonds and Ag⋯O inter­actions with an Ag⋯O separation of 2.869 (2) Å. In addition, the [AsF(6)](−) counter-anions are linked to the hydrazone groups through N—H⋯F hydrogen bonds. Four of the F atoms of the [AsF(6)](−) anion are disordered over two sets of sites with occupancies of 0.732 (9) and 0.268 (9). International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977146/ /pubmed/21583380 http://dx.doi.org/10.1107/S1600536809026907 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Cao-Yuan
Ning, Ai-Min
Kou, Chun-Hong
He, Yong
Fen, Zhi-Qiang
catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
title catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
title_full catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
title_fullStr catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
title_full_unstemmed catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
title_short catena-Poly[[[[N′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(I)]-μ-[N′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
title_sort catena-poly[[[[n′-(4-cyano­benzyl­idene)nicotinohydrazide]silver(i)]-μ-[n′-4-cyano­benzyl­idene)nicotinohydrazide]] hexa­fluoridoarsenate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977146/
https://www.ncbi.nlm.nih.gov/pubmed/21583380
http://dx.doi.org/10.1107/S1600536809026907
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