The iron phosphate CaFe(3)(PO(4))(3)O

A new iron phosphate, calcium triiron(III) tris­(phosphate) oxide, CaFe(3)(PO(4))(3)O, has been isolated and shown to exhibit a three-dimensional structure built by FeO(6) octa­hedra, FeO(5) trigonal bipyramids and PO(4) tetra­hedra. The FeO(x) (x = 5, 6) polyhedra are linked through common corners...

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Detalles Bibliográficos
Autores principales: Hidouri, Mourad, Ben Amara, Mongi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977148/
https://www.ncbi.nlm.nih.gov/pubmed/21583300
http://dx.doi.org/10.1107/S160053680902827X
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author Hidouri, Mourad
Ben Amara, Mongi
author_facet Hidouri, Mourad
Ben Amara, Mongi
author_sort Hidouri, Mourad
collection PubMed
description A new iron phosphate, calcium triiron(III) tris­(phosphate) oxide, CaFe(3)(PO(4))(3)O, has been isolated and shown to exhibit a three-dimensional structure built by FeO(6) octa­hedra, FeO(5) trigonal bipyramids and PO(4) tetra­hedra. The FeO(x) (x = 5, 6) polyhedra are linked through common corners and edges, forming [Fe(6)O(28)](∞) chains with branches running along [010]. Adjacent chains are connected by the phosphate groups via common corners and edges, giving rise to a three-dimensional framework analogous to those of the previously reported SrFe(3)(PO(4))(3)O and Bi(0.4)Fe(3)(PO(4))(3)O structures, in which the Ca(2+) cations occupy a single symmetry non-equivalent cavity.
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spelling pubmed-29771482010-12-30 The iron phosphate CaFe(3)(PO(4))(3)O Hidouri, Mourad Ben Amara, Mongi Acta Crystallogr Sect E Struct Rep Online Inorganic Papers A new iron phosphate, calcium triiron(III) tris­(phosphate) oxide, CaFe(3)(PO(4))(3)O, has been isolated and shown to exhibit a three-dimensional structure built by FeO(6) octa­hedra, FeO(5) trigonal bipyramids and PO(4) tetra­hedra. The FeO(x) (x = 5, 6) polyhedra are linked through common corners and edges, forming [Fe(6)O(28)](∞) chains with branches running along [010]. Adjacent chains are connected by the phosphate groups via common corners and edges, giving rise to a three-dimensional framework analogous to those of the previously reported SrFe(3)(PO(4))(3)O and Bi(0.4)Fe(3)(PO(4))(3)O structures, in which the Ca(2+) cations occupy a single symmetry non-equivalent cavity. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977148/ /pubmed/21583300 http://dx.doi.org/10.1107/S160053680902827X Text en © Hidouri and Ben amara 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Hidouri, Mourad
Ben Amara, Mongi
The iron phosphate CaFe(3)(PO(4))(3)O
title The iron phosphate CaFe(3)(PO(4))(3)O
title_full The iron phosphate CaFe(3)(PO(4))(3)O
title_fullStr The iron phosphate CaFe(3)(PO(4))(3)O
title_full_unstemmed The iron phosphate CaFe(3)(PO(4))(3)O
title_short The iron phosphate CaFe(3)(PO(4))(3)O
title_sort iron phosphate cafe(3)(po(4))(3)o
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977148/
https://www.ncbi.nlm.nih.gov/pubmed/21583300
http://dx.doi.org/10.1107/S160053680902827X
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