Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)

The asymmetric unit of the title compound, [CuCl(C(12)H(12)N(2)O)][CuCl(C(12)H(12)N(2)O)(H(2)O)](ClO(4))(2), contains two different discrete cations. In one cation, the Cu(II) ion is coordinated in a slightly distorted square-planar geometry, while in the other the Cu(II) ion is in a slightly distor...

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Detalles Bibliográficos
Autores principales: Li, Hong, Xie, Long Miao, Zhang, Shi Guo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977150/
https://www.ncbi.nlm.nih.gov/pubmed/21583386
http://dx.doi.org/10.1107/S1600536809027123
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author Li, Hong
Xie, Long Miao
Zhang, Shi Guo
author_facet Li, Hong
Xie, Long Miao
Zhang, Shi Guo
author_sort Li, Hong
collection PubMed
description The asymmetric unit of the title compound, [CuCl(C(12)H(12)N(2)O)][CuCl(C(12)H(12)N(2)O)(H(2)O)](ClO(4))(2), contains two different discrete cations. In one cation, the Cu(II) ion is coordinated in a slightly distorted square-planar geometry, while in the other the Cu(II) ion is in a slightly distorted square-pyramidal environment. In the crystal structure, there are O—H⋯O hydrogen bonds between coordinated water mol­ecules and perchlorate anions. Both types of cations are linked into one-dimensional chains along the b axis by weak electrostatic Cu⋯Cl inter­actions, with Cu⋯Cl distances of 2.8088 (16) and 3.2074 (17) Å.
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spelling pubmed-29771502010-12-30 Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1) Li, Hong Xie, Long Miao Zhang, Shi Guo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CuCl(C(12)H(12)N(2)O)][CuCl(C(12)H(12)N(2)O)(H(2)O)](ClO(4))(2), contains two different discrete cations. In one cation, the Cu(II) ion is coordinated in a slightly distorted square-planar geometry, while in the other the Cu(II) ion is in a slightly distorted square-pyramidal environment. In the crystal structure, there are O—H⋯O hydrogen bonds between coordinated water mol­ecules and perchlorate anions. Both types of cations are linked into one-dimensional chains along the b axis by weak electrostatic Cu⋯Cl inter­actions, with Cu⋯Cl distances of 2.8088 (16) and 3.2074 (17) Å. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977150/ /pubmed/21583386 http://dx.doi.org/10.1107/S1600536809027123 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong
Xie, Long Miao
Zhang, Shi Guo
Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)
title Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)
title_full Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)
title_fullStr Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)
title_full_unstemmed Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)
title_short Chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(II) perchlorate (1/1)
title_sort chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(ii) perchlorate–aqua­chlorido[2,2′-(oxydimethyl­ene)­dipyridine]copper(ii) perchlorate (1/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977150/
https://www.ncbi.nlm.nih.gov/pubmed/21583386
http://dx.doi.org/10.1107/S1600536809027123
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AT xielongmiao chlorido22oxydimethylenedipyridinecopperiiperchlorateaquachlorido22oxydimethylenedipyridinecopperiiperchlorate11
AT zhangshiguo chlorido22oxydimethylenedipyridinecopperiiperchlorateaquachlorido22oxydimethylenedipyridinecopperiiperchlorate11

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