Cargando…
catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate]
The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydrothermal reaction of manganese chloride with mixed 3-hydroxylcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977154/ https://www.ncbi.nlm.nih.gov/pubmed/21583422 http://dx.doi.org/10.1107/S1600536809028360 |
Sumario: | The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydrothermal reaction of manganese chloride with mixed 3-hydroxylcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4′-bipy ligands, surrounded by HL (−) anions and uncoordinated water molecules. Extensive O—H⋯O hydrogen-bonding and weak π–π interactions [centroid–centroid distance = 3.7572 (3) Å] between the constituents lead to the formation of a three-dimensional supramolecular network. |
---|