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catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]

The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydro­thermal reaction of manganese chloride with mixed 3-hydroxy­lcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with...

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Detalles Bibliográficos
Autores principales: Tang, Zhi-Wei, Fu, Jun-Dan, Jiang, Long-Ping, Wen, Yi-Hang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977154/
https://www.ncbi.nlm.nih.gov/pubmed/21583422
http://dx.doi.org/10.1107/S1600536809028360
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author Tang, Zhi-Wei
Fu, Jun-Dan
Jiang, Long-Ping
Wen, Yi-Hang
author_facet Tang, Zhi-Wei
Fu, Jun-Dan
Jiang, Long-Ping
Wen, Yi-Hang
author_sort Tang, Zhi-Wei
collection PubMed
description The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydro­thermal reaction of manganese chloride with mixed 3-hydroxy­lcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4′-bipy ligands, surrounded by HL (−) anions and uncoordinated water mol­ecules. Extensive O—H⋯O hydrogen-bonding and weak π–π inter­actions [centroid–centroid distance = 3.7572  (3) Å] between the constituents lead to the formation of a three-dimensional supra­molecular network.
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spelling pubmed-29771542010-12-30 catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate] Tang, Zhi-Wei Fu, Jun-Dan Jiang, Long-Ping Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydro­thermal reaction of manganese chloride with mixed 3-hydroxy­lcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4′-bipy ligands, surrounded by HL (−) anions and uncoordinated water mol­ecules. Extensive O—H⋯O hydrogen-bonding and weak π–π inter­actions [centroid–centroid distance = 3.7572  (3) Å] between the constituents lead to the formation of a three-dimensional supra­molecular network. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977154/ /pubmed/21583422 http://dx.doi.org/10.1107/S1600536809028360 Text en © Tang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Zhi-Wei
Fu, Jun-Dan
Jiang, Long-Ping
Wen, Yi-Hang
catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
title catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
title_full catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
title_fullStr catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
title_full_unstemmed catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
title_short catena-Poly[[[tetra­aqua­manganese(II)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
title_sort catena-poly[[[tetra­aqua­manganese(ii)]-μ-4,4′-bipyridine] bis­(3-hydroxy­cinnamate) dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977154/
https://www.ncbi.nlm.nih.gov/pubmed/21583422
http://dx.doi.org/10.1107/S1600536809028360
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