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catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate]
The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydrothermal reaction of manganese chloride with mixed 3-hydroxylcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977154/ https://www.ncbi.nlm.nih.gov/pubmed/21583422 http://dx.doi.org/10.1107/S1600536809028360 |
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author | Tang, Zhi-Wei Fu, Jun-Dan Jiang, Long-Ping Wen, Yi-Hang |
author_facet | Tang, Zhi-Wei Fu, Jun-Dan Jiang, Long-Ping Wen, Yi-Hang |
author_sort | Tang, Zhi-Wei |
collection | PubMed |
description | The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydrothermal reaction of manganese chloride with mixed 3-hydroxylcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4′-bipy ligands, surrounded by HL (−) anions and uncoordinated water molecules. Extensive O—H⋯O hydrogen-bonding and weak π–π interactions [centroid–centroid distance = 3.7572 (3) Å] between the constituents lead to the formation of a three-dimensional supramolecular network. |
format | Text |
id | pubmed-2977154 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771542010-12-30 catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] Tang, Zhi-Wei Fu, Jun-Dan Jiang, Long-Ping Wen, Yi-Hang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Mn(C(10)H(8)N(2))(H(2)O)(4)](C(9)H(7)O(3))(2)·2H(2)O}(n), was obtained by the hydrothermal reaction of manganese chloride with mixed 3-hydroxylcinnamic acid (H(2) L) and 4,4′-bipyridine (4,4′-bipy) ligands. The structure contains [Mn(C(10)H(8)N(2))(H(2)O)(4)](2+) cations with the Mn(II) atoms lying on a centres of inversion and bridged into a linear chain along the a axis by 4,4′-bipy ligands, surrounded by HL (−) anions and uncoordinated water molecules. Extensive O—H⋯O hydrogen-bonding and weak π–π interactions [centroid–centroid distance = 3.7572 (3) Å] between the constituents lead to the formation of a three-dimensional supramolecular network. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977154/ /pubmed/21583422 http://dx.doi.org/10.1107/S1600536809028360 Text en © Tang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tang, Zhi-Wei Fu, Jun-Dan Jiang, Long-Ping Wen, Yi-Hang catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
title |
catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
title_full |
catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
title_fullStr |
catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
title_full_unstemmed |
catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
title_short |
catena-Poly[[[tetraaquamanganese(II)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
title_sort | catena-poly[[[tetraaquamanganese(ii)]-μ-4,4′-bipyridine] bis(3-hydroxycinnamate) dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977154/ https://www.ncbi.nlm.nih.gov/pubmed/21583422 http://dx.doi.org/10.1107/S1600536809028360 |
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