trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)

The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal–carbonyl complex containing an Ru—Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo­penta­dienyl group. The complex h...

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Detalles Bibliográficos
Autores principales: Ma, Zhi-Hong, Dong, Gui-Ying, Liu, Xiao-Huan, Lin, Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977155/
https://www.ncbi.nlm.nih.gov/pubmed/21583356
http://dx.doi.org/10.1107/S1600536809026063
Descripción
Sumario:The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal–carbonyl complex containing an Ru—Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo­penta­dienyl group. The complex has a trans conformation and the two cyclo­penta­dienyl ring planes are parallel. The crystal structure involves weak C—H⋯O hydrogen bonds.

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