trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)

The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal–carbonyl complex containing an Ru—Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo­penta­dienyl group. The complex h...

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Detalles Bibliográficos
Autores principales: Ma, Zhi-Hong, Dong, Gui-Ying, Liu, Xiao-Huan, Lin, Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977155/
https://www.ncbi.nlm.nih.gov/pubmed/21583356
http://dx.doi.org/10.1107/S1600536809026063
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author Ma, Zhi-Hong
Dong, Gui-Ying
Liu, Xiao-Huan
Lin, Jin
author_facet Ma, Zhi-Hong
Dong, Gui-Ying
Liu, Xiao-Huan
Lin, Jin
author_sort Ma, Zhi-Hong
collection PubMed
description The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal–carbonyl complex containing an Ru—Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo­penta­dienyl group. The complex has a trans conformation and the two cyclo­penta­dienyl ring planes are parallel. The crystal structure involves weak C—H⋯O hydrogen bonds.
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spelling pubmed-29771552010-12-30 trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru) Ma, Zhi-Hong Dong, Gui-Ying Liu, Xiao-Huan Lin, Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(2)(C(13)H(15)S)(2)(CO)(4)], is a centrosymmetric binuclear metal–carbonyl complex containing an Ru—Ru single bond [2.7511 (8) Å]. Each Ru(I) atom is coordinated by two bridging carbonyl ligands, one terminal carbonyl ligand and one η(5)-cyclo­penta­dienyl group. The complex has a trans conformation and the two cyclo­penta­dienyl ring planes are parallel. The crystal structure involves weak C—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977155/ /pubmed/21583356 http://dx.doi.org/10.1107/S1600536809026063 Text en © Ma et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Zhi-Hong
Dong, Gui-Ying
Liu, Xiao-Huan
Lin, Jin
trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_full trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_fullStr trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_full_unstemmed trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_short trans-Di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(I)}(Ru—Ru)
title_sort trans-di-μ-carbonyl-bis­{carbon­yl[η(5)-2,3,4,5-tetra­methyl-1-(2-thien­yl)cyclo­penta­dien­yl]ruthenium(i)}(ru—ru)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977155/
https://www.ncbi.nlm.nih.gov/pubmed/21583356
http://dx.doi.org/10.1107/S1600536809026063
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AT dongguiying transdimcarbonylbiscarbonylē52345tetramethyl12thienylcyclopentadienylrutheniumiruru
AT liuxiaohuan transdimcarbonylbiscarbonylē52345tetramethyl12thienylcyclopentadienylrutheniumiruru
AT linjin transdimcarbonylbiscarbonylē52345tetramethyl12thienylcyclopentadienylrutheniumiruru

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