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4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine
The title compound, C(6)H(8)N(6), crystallizes as an N—H⋯N hydrogen-bond-linked dimer of two almost identical molecules in the asymmetric unit. Both of the molecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyr...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977168/ https://www.ncbi.nlm.nih.gov/pubmed/21583438 http://dx.doi.org/10.1107/S1600536809023952 |
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author | Dolzhenko, Anton V. Pastorin, Giorgia Dolzhenko, Anna V. Tan, Geok Kheng Koh, Lip Lin |
author_facet | Dolzhenko, Anton V. Pastorin, Giorgia Dolzhenko, Anna V. Tan, Geok Kheng Koh, Lip Lin |
author_sort | Dolzhenko, Anton V. |
collection | PubMed |
description | The title compound, C(6)H(8)N(6), crystallizes as an N—H⋯N hydrogen-bond-linked dimer of two almost identical molecules in the asymmetric unit. Both of the molecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyrazole rings. The dimers are arranged into chains via intermolecular N—H⋯N hydrogen bonds between the hydrazino groups and the N atoms of the pyrimidine rings of both types of the molecules, linking the molecules into a C(7) graph-set motif along [100]. The methyl groups and the N atoms of the pyrazole rings form weak C—H⋯N hydrogen bonds, which connect chains of the dimers in a C(4) motif parallel to [100]. |
format | Text |
id | pubmed-2977168 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771682010-12-30 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine Dolzhenko, Anton V. Pastorin, Giorgia Dolzhenko, Anna V. Tan, Geok Kheng Koh, Lip Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(8)N(6), crystallizes as an N—H⋯N hydrogen-bond-linked dimer of two almost identical molecules in the asymmetric unit. Both of the molecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyrazole rings. The dimers are arranged into chains via intermolecular N—H⋯N hydrogen bonds between the hydrazino groups and the N atoms of the pyrimidine rings of both types of the molecules, linking the molecules into a C(7) graph-set motif along [100]. The methyl groups and the N atoms of the pyrazole rings form weak C—H⋯N hydrogen bonds, which connect chains of the dimers in a C(4) motif parallel to [100]. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977168/ /pubmed/21583438 http://dx.doi.org/10.1107/S1600536809023952 Text en © Dolzhenko et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Dolzhenko, Anton V. Pastorin, Giorgia Dolzhenko, Anna V. Tan, Geok Kheng Koh, Lip Lin 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
title | 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
title_full | 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
title_fullStr | 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
title_full_unstemmed | 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
title_short | 4-Hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
title_sort | 4-hydrazino-1-methylpyrazolo[3,4-d]pyrimidine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977168/ https://www.ncbi.nlm.nih.gov/pubmed/21583438 http://dx.doi.org/10.1107/S1600536809023952 |
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