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4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine

The title compound, C(6)H(8)N(6), crystallizes as an N—H⋯N hydrogen-bond-linked dimer of two almost identical mol­ecules in the asymmetric unit. Both of the mol­ecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyr...

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Autores principales: Dolzhenko, Anton V., Pastorin, Giorgia, Dolzhenko, Anna V., Tan, Geok Kheng, Koh, Lip Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977168/
https://www.ncbi.nlm.nih.gov/pubmed/21583438
http://dx.doi.org/10.1107/S1600536809023952
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author Dolzhenko, Anton V.
Pastorin, Giorgia
Dolzhenko, Anna V.
Tan, Geok Kheng
Koh, Lip Lin
author_facet Dolzhenko, Anton V.
Pastorin, Giorgia
Dolzhenko, Anna V.
Tan, Geok Kheng
Koh, Lip Lin
author_sort Dolzhenko, Anton V.
collection PubMed
description The title compound, C(6)H(8)N(6), crystallizes as an N—H⋯N hydrogen-bond-linked dimer of two almost identical mol­ecules in the asymmetric unit. Both of the mol­ecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyrazole rings. The dimers are arranged into chains via inter­molecular N—H⋯N hydrogen bonds between the hydrazino groups and the N atoms of the pyrimidine rings of both types of the mol­ecules, linking the mol­ecules into a C(7) graph-set motif along [100]. The methyl groups and the N atoms of the pyrazole rings form weak C—H⋯N hydrogen bonds, which connect chains of the dimers in a C(4) motif parallel to [100].
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spelling pubmed-29771682010-12-30 4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine Dolzhenko, Anton V. Pastorin, Giorgia Dolzhenko, Anna V. Tan, Geok Kheng Koh, Lip Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(8)N(6), crystallizes as an N—H⋯N hydrogen-bond-linked dimer of two almost identical mol­ecules in the asymmetric unit. Both of the mol­ecules are almost planar (rms deviations of 0.0186 and 0.0296 Å in the two molecules) and their hydrazino groups are turned towards the pyrazole rings. The dimers are arranged into chains via inter­molecular N—H⋯N hydrogen bonds between the hydrazino groups and the N atoms of the pyrimidine rings of both types of the mol­ecules, linking the mol­ecules into a C(7) graph-set motif along [100]. The methyl groups and the N atoms of the pyrazole rings form weak C—H⋯N hydrogen bonds, which connect chains of the dimers in a C(4) motif parallel to [100]. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977168/ /pubmed/21583438 http://dx.doi.org/10.1107/S1600536809023952 Text en © Dolzhenko et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dolzhenko, Anton V.
Pastorin, Giorgia
Dolzhenko, Anna V.
Tan, Geok Kheng
Koh, Lip Lin
4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
title 4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
title_full 4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
title_fullStr 4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
title_full_unstemmed 4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
title_short 4-Hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
title_sort 4-hydrazino-1-methyl­pyrazolo[3,4-d]pyrimidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977168/
https://www.ncbi.nlm.nih.gov/pubmed/21583438
http://dx.doi.org/10.1107/S1600536809023952
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