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Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]

In the crystal structure of the title compound, [Cu(2)(CH(3)COO)(4)(C(9)H(7)N)(2)], the Cu(II) cation is coordinated by four acetate anions and one isoquinoline mol­ecule in a distorted square-pyramidal geometry; the Cu(II) cation is 0.1681 (6) Å from the basal coordination plane formed by the four...

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Detalles Bibliográficos
Autores principales: Li, Meng-Jiao, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977170/
https://www.ncbi.nlm.nih.gov/pubmed/21583345
http://dx.doi.org/10.1107/S1600536809025732
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author Li, Meng-Jiao
Nie, Jing-Jing
Xu, Duan-Jun
author_facet Li, Meng-Jiao
Nie, Jing-Jing
Xu, Duan-Jun
author_sort Li, Meng-Jiao
collection PubMed
description In the crystal structure of the title compound, [Cu(2)(CH(3)COO)(4)(C(9)H(7)N)(2)], the Cu(II) cation is coordinated by four acetate anions and one isoquinoline mol­ecule in a distorted square-pyramidal geometry; the Cu(II) cation is 0.1681 (6) Å from the basal coordination plane formed by the four O atoms. Each acetate anion bridges two Cu(II) cations to form the centrosymmetric dinuclear complex. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.6459 (4) Å. A parallel arrangement of isoquinoline ligands of adjacent complexes is observed in the crystal structure; the face-to-face distance of 3.610 (10) Å suggests there is no π–π stacking between isoquinoline ring systems.
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spelling pubmed-29771702010-12-30 Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)] Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(2)(CH(3)COO)(4)(C(9)H(7)N)(2)], the Cu(II) cation is coordinated by four acetate anions and one isoquinoline mol­ecule in a distorted square-pyramidal geometry; the Cu(II) cation is 0.1681 (6) Å from the basal coordination plane formed by the four O atoms. Each acetate anion bridges two Cu(II) cations to form the centrosymmetric dinuclear complex. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.6459 (4) Å. A parallel arrangement of isoquinoline ligands of adjacent complexes is observed in the crystal structure; the face-to-face distance of 3.610 (10) Å suggests there is no π–π stacking between isoquinoline ring systems. International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977170/ /pubmed/21583345 http://dx.doi.org/10.1107/S1600536809025732 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Meng-Jiao
Nie, Jing-Jing
Xu, Duan-Jun
Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]
title Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]
title_full Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]
title_fullStr Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]
title_full_unstemmed Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]
title_short Tetra-μ(2)-acetato-κ(8) O:O′-bis­[(isoquinoline-κN)copper(II)]
title_sort tetra-μ(2)-acetato-κ(8) o:o′-bis­[(isoquinoline-κn)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977170/
https://www.ncbi.nlm.nih.gov/pubmed/21583345
http://dx.doi.org/10.1107/S1600536809025732
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