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Tetra-μ(2)-acetato-κ(8) O:O′-bis[(isoquinoline-κN)copper(II)]
In the crystal structure of the title compound, [Cu(2)(CH(3)COO)(4)(C(9)H(7)N)(2)], the Cu(II) cation is coordinated by four acetate anions and one isoquinoline molecule in a distorted square-pyramidal geometry; the Cu(II) cation is 0.1681 (6) Å from the basal coordination plane formed by the four...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977170/ https://www.ncbi.nlm.nih.gov/pubmed/21583345 http://dx.doi.org/10.1107/S1600536809025732 |
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author | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
author_facet | Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun |
author_sort | Li, Meng-Jiao |
collection | PubMed |
description | In the crystal structure of the title compound, [Cu(2)(CH(3)COO)(4)(C(9)H(7)N)(2)], the Cu(II) cation is coordinated by four acetate anions and one isoquinoline molecule in a distorted square-pyramidal geometry; the Cu(II) cation is 0.1681 (6) Å from the basal coordination plane formed by the four O atoms. Each acetate anion bridges two Cu(II) cations to form the centrosymmetric dinuclear complex. Within the dinuclear molecule, the Cu⋯Cu separation is 2.6459 (4) Å. A parallel arrangement of isoquinoline ligands of adjacent complexes is observed in the crystal structure; the face-to-face distance of 3.610 (10) Å suggests there is no π–π stacking between isoquinoline ring systems. |
format | Text |
id | pubmed-2977170 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771702010-12-30 Tetra-μ(2)-acetato-κ(8) O:O′-bis[(isoquinoline-κN)copper(II)] Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(2)(CH(3)COO)(4)(C(9)H(7)N)(2)], the Cu(II) cation is coordinated by four acetate anions and one isoquinoline molecule in a distorted square-pyramidal geometry; the Cu(II) cation is 0.1681 (6) Å from the basal coordination plane formed by the four O atoms. Each acetate anion bridges two Cu(II) cations to form the centrosymmetric dinuclear complex. Within the dinuclear molecule, the Cu⋯Cu separation is 2.6459 (4) Å. A parallel arrangement of isoquinoline ligands of adjacent complexes is observed in the crystal structure; the face-to-face distance of 3.610 (10) Å suggests there is no π–π stacking between isoquinoline ring systems. International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977170/ /pubmed/21583345 http://dx.doi.org/10.1107/S1600536809025732 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Meng-Jiao Nie, Jing-Jing Xu, Duan-Jun Tetra-μ(2)-acetato-κ(8) O:O′-bis[(isoquinoline-κN)copper(II)] |
title | Tetra-μ(2)-acetato-κ(8)
O:O′-bis[(isoquinoline-κN)copper(II)] |
title_full | Tetra-μ(2)-acetato-κ(8)
O:O′-bis[(isoquinoline-κN)copper(II)] |
title_fullStr | Tetra-μ(2)-acetato-κ(8)
O:O′-bis[(isoquinoline-κN)copper(II)] |
title_full_unstemmed | Tetra-μ(2)-acetato-κ(8)
O:O′-bis[(isoquinoline-κN)copper(II)] |
title_short | Tetra-μ(2)-acetato-κ(8)
O:O′-bis[(isoquinoline-κN)copper(II)] |
title_sort | tetra-μ(2)-acetato-κ(8)
o:o′-bis[(isoquinoline-κn)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977170/ https://www.ncbi.nlm.nih.gov/pubmed/21583345 http://dx.doi.org/10.1107/S1600536809025732 |
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