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Diaquabis(N,N-diethylnicotinamide-κN (1))bis[4-(dimethylamino)benzoato-κO]nickel(II)
The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethylaminobenzoate (DMAB), two diethylnicotinamide (DENA) ligands and two water molecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom for...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977174/ https://www.ncbi.nlm.nih.gov/pubmed/21583312 http://dx.doi.org/10.1107/S1600536809030098 |
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author | Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethylaminobenzoate (DMAB), two diethylnicotinamide (DENA) ligands and two water molecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni(II) atom is displaced by 0.681 (1) Å out of the least-squares plane of the carboxylate group. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.61 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20 (4)°. An intramolecular O—H⋯O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link molecules into a three-dimensional network. Two weak C—H⋯π interactions are also present. |
format | Text |
id | pubmed-2977174 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771742010-12-30 Diaquabis(N,N-diethylnicotinamide-κN (1))bis[4-(dimethylamino)benzoato-κO]nickel(II) Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethylaminobenzoate (DMAB), two diethylnicotinamide (DENA) ligands and two water molecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni(II) atom is displaced by 0.681 (1) Å out of the least-squares plane of the carboxylate group. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.61 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20 (4)°. An intramolecular O—H⋯O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link molecules into a three-dimensional network. Two weak C—H⋯π interactions are also present. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977174/ /pubmed/21583312 http://dx.doi.org/10.1107/S1600536809030098 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Diaquabis(N,N-diethylnicotinamide-κN (1))bis[4-(dimethylamino)benzoato-κO]nickel(II) |
title | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]nickel(II) |
title_full | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]nickel(II) |
title_fullStr | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]nickel(II) |
title_full_unstemmed | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]nickel(II) |
title_short | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis[4-(dimethylamino)benzoato-κO]nickel(II) |
title_sort | diaquabis(n,n-diethylnicotinamide-κn
(1))bis[4-(dimethylamino)benzoato-κo]nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977174/ https://www.ncbi.nlm.nih.gov/pubmed/21583312 http://dx.doi.org/10.1107/S1600536809030098 |
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