Cargando…

Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)

The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethyl­amino­benzoate (DMAB), two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom for...

Descripción completa

Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Süzen, Yasemin, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977174/
https://www.ncbi.nlm.nih.gov/pubmed/21583312
http://dx.doi.org/10.1107/S1600536809030098
_version_ 1782191045097816064
author Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethyl­amino­benzoate (DMAB), two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni(II) atom is displaced by 0.681 (1) Å out of the least-squares plane of the carboxyl­ate group. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 5.61 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20 (4)°. An intra­molecular O—H⋯O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present.
format Text
id pubmed-2977174
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29771742010-12-30 Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II) Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The centrosymmetric title Ni(II) complex, [Ni(C(9)H(10)NO(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two dimethyl­amino­benzoate (DMAB), two diethyl­nicotinamide (DENA) ligands and two water mol­ecules, all of them monodentate. The four O atoms in the equatorial plane around the Ni(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The Ni(II) atom is displaced by 0.681 (1) Å out of the least-squares plane of the carboxyl­ate group. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 5.61 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 73.20 (4)°. An intra­molecular O—H⋯O hydrogen bond results in the formation of a six-membered ring with a twisted conformation. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link mol­ecules into a three-dimensional network. Two weak C—H⋯π inter­actions are also present. International Union of Crystallography 2009-07-31 /pmc/articles/PMC2977174/ /pubmed/21583312 http://dx.doi.org/10.1107/S1600536809030098 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)
title Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)
title_full Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)
title_fullStr Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)
title_full_unstemmed Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)
title_short Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­[4-(dimethyl­amino)benzoato-κO]nickel(II)
title_sort diaqua­bis(n,n-diethyl­nicotinamide-κn (1))bis­[4-(dimethyl­amino)benzoato-κo]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977174/
https://www.ncbi.nlm.nih.gov/pubmed/21583312
http://dx.doi.org/10.1107/S1600536809030098
work_keys_str_mv AT hokelektuncer diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokonickelii
AT suzenyasemin diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokonickelii
AT tercanbarıs diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokonickelii
AT aybirdiozgur diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokonickelii
AT necefogluhacali diaquabisnndiethylnicotinamidekn1bis4dimethylaminobenzoatokonickelii