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2-Iodo-1,3-dimethoxy­benzene

Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxy­benzoic acid and iodo­benzene diacetate under a nitro­gen atmosphere at 353 K. In the crystal structure, mol­ecules are linked by weak C—H⋯π inter­actions, generating inter­penetrating on...

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Detalles Bibliográficos
Autores principales: Xue, Li-Ping, Qin, Jian-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977187/
https://www.ncbi.nlm.nih.gov/pubmed/21583496
http://dx.doi.org/10.1107/S1600536809025264
Descripción
Sumario:Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxy­benzoic acid and iodo­benzene diacetate under a nitro­gen atmosphere at 353 K. In the crystal structure, mol­ecules are linked by weak C—H⋯π inter­actions, generating inter­penetrating one-dimensional chains of perpendicularly oriented mol­ecules extending along [011] and [0[Image: see text]1]. Chains are also formed through non-bonding C—I⋯π contacts extending in the same directions, projecting a zigzag motif in view down [100]. The I⋯Cg distance is 3.695 (2) Å and the C—I⋯Cg angle is 164.17 (14)°. The mol­ecular symmetry m coincides with the mirror plane of the space group Cmc2(1), resulting in a half-mol­ecule in the asymmetric unit (Z′ = ½).