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2-Iodo-1,3-dimethoxybenzene
Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxybenzoic acid and iodobenzene diacetate under a nitrogen atmosphere at 353 K. In the crystal structure, molecules are linked by weak C—H⋯π interactions, generating interpenetrating on...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977187/ https://www.ncbi.nlm.nih.gov/pubmed/21583496 http://dx.doi.org/10.1107/S1600536809025264 |
Sumario: | Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxybenzoic acid and iodobenzene diacetate under a nitrogen atmosphere at 353 K. In the crystal structure, molecules are linked by weak C—H⋯π interactions, generating interpenetrating one-dimensional chains of perpendicularly oriented molecules extending along [011] and [0[Image: see text]1]. Chains are also formed through non-bonding C—I⋯π contacts extending in the same directions, projecting a zigzag motif in view down [100]. The I⋯Cg distance is 3.695 (2) Å and the C—I⋯Cg angle is 164.17 (14)°. The molecular symmetry m coincides with the mirror plane of the space group Cmc2(1), resulting in a half-molecule in the asymmetric unit (Z′ = ½). |
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