Cargando…

2-Iodo-1,3-dimethoxy­benzene

Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxy­benzoic acid and iodo­benzene diacetate under a nitro­gen atmosphere at 353 K. In the crystal structure, mol­ecules are linked by weak C—H⋯π inter­actions, generating inter­penetrating on...

Descripción completa

Detalles Bibliográficos
Autores principales: Xue, Li-Ping, Qin, Jian-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977187/
https://www.ncbi.nlm.nih.gov/pubmed/21583496
http://dx.doi.org/10.1107/S1600536809025264
_version_ 1782191048217329664
author Xue, Li-Ping
Qin, Jian-Hua
author_facet Xue, Li-Ping
Qin, Jian-Hua
author_sort Xue, Li-Ping
collection PubMed
description Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxy­benzoic acid and iodo­benzene diacetate under a nitro­gen atmosphere at 353 K. In the crystal structure, mol­ecules are linked by weak C—H⋯π inter­actions, generating inter­penetrating one-dimensional chains of perpendicularly oriented mol­ecules extending along [011] and [0[Image: see text]1]. Chains are also formed through non-bonding C—I⋯π contacts extending in the same directions, projecting a zigzag motif in view down [100]. The I⋯Cg distance is 3.695 (2) Å and the C—I⋯Cg angle is 164.17 (14)°. The mol­ecular symmetry m coincides with the mirror plane of the space group Cmc2(1), resulting in a half-mol­ecule in the asymmetric unit (Z′ = ½).
format Text
id pubmed-2977187
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29771872010-12-30 2-Iodo-1,3-dimethoxy­benzene Xue, Li-Ping Qin, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxy­benzoic acid and iodo­benzene diacetate under a nitro­gen atmosphere at 353 K. In the crystal structure, mol­ecules are linked by weak C—H⋯π inter­actions, generating inter­penetrating one-dimensional chains of perpendicularly oriented mol­ecules extending along [011] and [0[Image: see text]1]. Chains are also formed through non-bonding C—I⋯π contacts extending in the same directions, projecting a zigzag motif in view down [100]. The I⋯Cg distance is 3.695 (2) Å and the C—I⋯Cg angle is 164.17 (14)°. The mol­ecular symmetry m coincides with the mirror plane of the space group Cmc2(1), resulting in a half-mol­ecule in the asymmetric unit (Z′ = ½). International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977187/ /pubmed/21583496 http://dx.doi.org/10.1107/S1600536809025264 Text en © Xue and Qin 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xue, Li-Ping
Qin, Jian-Hua
2-Iodo-1,3-dimethoxy­benzene
title 2-Iodo-1,3-dimethoxy­benzene
title_full 2-Iodo-1,3-dimethoxy­benzene
title_fullStr 2-Iodo-1,3-dimethoxy­benzene
title_full_unstemmed 2-Iodo-1,3-dimethoxy­benzene
title_short 2-Iodo-1,3-dimethoxy­benzene
title_sort 2-iodo-1,3-dimethoxy­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977187/
https://www.ncbi.nlm.nih.gov/pubmed/21583496
http://dx.doi.org/10.1107/S1600536809025264
work_keys_str_mv AT xueliping 2iodo13dimethoxybenzene
AT qinjianhua 2iodo13dimethoxybenzene