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2-Iodo-1,3-dimethoxybenzene
Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxybenzoic acid and iodobenzene diacetate under a nitrogen atmosphere at 353 K. In the crystal structure, molecules are linked by weak C—H⋯π interactions, generating interpenetrating on...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977187/ https://www.ncbi.nlm.nih.gov/pubmed/21583496 http://dx.doi.org/10.1107/S1600536809025264 |
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author | Xue, Li-Ping Qin, Jian-Hua |
author_facet | Xue, Li-Ping Qin, Jian-Hua |
author_sort | Xue, Li-Ping |
collection | PubMed |
description | Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxybenzoic acid and iodobenzene diacetate under a nitrogen atmosphere at 353 K. In the crystal structure, molecules are linked by weak C—H⋯π interactions, generating interpenetrating one-dimensional chains of perpendicularly oriented molecules extending along [011] and [0[Image: see text]1]. Chains are also formed through non-bonding C—I⋯π contacts extending in the same directions, projecting a zigzag motif in view down [100]. The I⋯Cg distance is 3.695 (2) Å and the C—I⋯Cg angle is 164.17 (14)°. The molecular symmetry m coincides with the mirror plane of the space group Cmc2(1), resulting in a half-molecule in the asymmetric unit (Z′ = ½). |
format | Text |
id | pubmed-2977187 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29771872010-12-30 2-Iodo-1,3-dimethoxybenzene Xue, Li-Ping Qin, Jian-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(8)H(9)IO(2), were obtained from a dimethyl sulfoxide solution of 2,6-dimethoxybenzoic acid and iodobenzene diacetate under a nitrogen atmosphere at 353 K. In the crystal structure, molecules are linked by weak C—H⋯π interactions, generating interpenetrating one-dimensional chains of perpendicularly oriented molecules extending along [011] and [0[Image: see text]1]. Chains are also formed through non-bonding C—I⋯π contacts extending in the same directions, projecting a zigzag motif in view down [100]. The I⋯Cg distance is 3.695 (2) Å and the C—I⋯Cg angle is 164.17 (14)°. The molecular symmetry m coincides with the mirror plane of the space group Cmc2(1), resulting in a half-molecule in the asymmetric unit (Z′ = ½). International Union of Crystallography 2009-07-08 /pmc/articles/PMC2977187/ /pubmed/21583496 http://dx.doi.org/10.1107/S1600536809025264 Text en © Xue and Qin 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Xue, Li-Ping Qin, Jian-Hua 2-Iodo-1,3-dimethoxybenzene |
title | 2-Iodo-1,3-dimethoxybenzene |
title_full | 2-Iodo-1,3-dimethoxybenzene |
title_fullStr | 2-Iodo-1,3-dimethoxybenzene |
title_full_unstemmed | 2-Iodo-1,3-dimethoxybenzene |
title_short | 2-Iodo-1,3-dimethoxybenzene |
title_sort | 2-iodo-1,3-dimethoxybenzene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977187/ https://www.ncbi.nlm.nih.gov/pubmed/21583496 http://dx.doi.org/10.1107/S1600536809025264 |
work_keys_str_mv | AT xueliping 2iodo13dimethoxybenzene AT qinjianhua 2iodo13dimethoxybenzene |