Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)

In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa­hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands...

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Detalles Bibliográficos
Autores principales: Schultz, Madeleine, Roa, Elnor C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977190/
https://www.ncbi.nlm.nih.gov/pubmed/21583424
http://dx.doi.org/10.1107/S160053680902858X
Descripción
Sumario:In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa­hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands are arranged around the periphery of the mol­ecule with a mer geometry of the S atoms.

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