Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)

In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa­hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands...

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Detalles Bibliográficos
Autores principales: Schultz, Madeleine, Roa, Elnor C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977190/
https://www.ncbi.nlm.nih.gov/pubmed/21583424
http://dx.doi.org/10.1107/S160053680902858X
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author Schultz, Madeleine
Roa, Elnor C.
author_facet Schultz, Madeleine
Roa, Elnor C.
author_sort Schultz, Madeleine
collection PubMed
description In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa­hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands are arranged around the periphery of the mol­ecule with a mer geometry of the S atoms.
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spelling pubmed-29771902010-12-30 Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1) Schultz, Madeleine Roa, Elnor C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(C(8)H(4)F(3)O(2)S)(3)](3)[Fe(C(8)H(4)F(3)O(2)S)(3)], the metal centre is statistically occupied by Al(III) and Fe(III) cations in a 3:1 ratio. The metal centre is within an octa­hedral O(6) donor set defined by three chelating substituted acetoacetonate anions. The ligands are arranged around the periphery of the mol­ecule with a mer geometry of the S atoms. International Union of Crystallography 2009-07-25 /pmc/articles/PMC2977190/ /pubmed/21583424 http://dx.doi.org/10.1107/S160053680902858X Text en © Schultz and Roa 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schultz, Madeleine
Roa, Elnor C.
Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)
title Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)
title_full Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)
title_fullStr Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)
title_full_unstemmed Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)
title_short Tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(III)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(III) (3/1)
title_sort tris[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dionato]aluminium(iii)–tris­[4,4,4-trifluoro-1-(2-thien­yl)butane-1,3-dion­ato]iron(iii) (3/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977190/
https://www.ncbi.nlm.nih.gov/pubmed/21583424
http://dx.doi.org/10.1107/S160053680902858X
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AT roaelnorc tris444trifluoro12thienylbutane13dionatoaluminiumiiitris444trifluoro12thienylbutane13dionatoironiii31

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