Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate

In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl­phosphine ligands and one water mol­ecule in a distorted trigonal geometry. In the BF(4) (−) anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy...

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Detalles Bibliográficos
Autores principales: Dai, Yanfeng, Zhang, Yi, Tian, Jianwen, Liu, Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977191/
https://www.ncbi.nlm.nih.gov/pubmed/21583302
http://dx.doi.org/10.1107/S1600536809029559
Descripción
Sumario:In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl­phosphine ligands and one water mol­ecule in a distorted trigonal geometry. In the BF(4) (−) anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu⋯F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter­action. O—H⋯F and weak C—H⋯F hydrogen bonding is present in the crystal structure.

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