Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate

In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl­phosphine ligands and one water mol­ecule in a distorted trigonal geometry. In the BF(4) (−) anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy...

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Detalles Bibliográficos
Autores principales: Dai, Yanfeng, Zhang, Yi, Tian, Jianwen, Liu, Zhen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977191/
https://www.ncbi.nlm.nih.gov/pubmed/21583302
http://dx.doi.org/10.1107/S1600536809029559
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author Dai, Yanfeng
Zhang, Yi
Tian, Jianwen
Liu, Zhen
author_facet Dai, Yanfeng
Zhang, Yi
Tian, Jianwen
Liu, Zhen
author_sort Dai, Yanfeng
collection PubMed
description In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl­phosphine ligands and one water mol­ecule in a distorted trigonal geometry. In the BF(4) (−) anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu⋯F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter­action. O—H⋯F and weak C—H⋯F hydrogen bonding is present in the crystal structure.
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spelling pubmed-29771912010-12-30 Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate Dai, Yanfeng Zhang, Yi Tian, Jianwen Liu, Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(18)H(15)P)(2)(H(2)O)]BF(4), the Cu(I) atom is coordinated by two P atoms from triphenyl­phosphine ligands and one water mol­ecule in a distorted trigonal geometry. In the BF(4) (−) anion, three F atoms are disordered over two sites around the B—F bond, the site-occupancy ratio being 0.67 (6):0.33 (6). The Cu⋯F distance of 2.602 (5) Å between the Cu atom and the ordered F atom may suggest a weak but genuine inter­action. O—H⋯F and weak C—H⋯F hydrogen bonding is present in the crystal structure. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977191/ /pubmed/21583302 http://dx.doi.org/10.1107/S1600536809029559 Text en © Dai et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Yanfeng
Zhang, Yi
Tian, Jianwen
Liu, Zhen
Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate
title Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate
title_full Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate
title_fullStr Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate
title_full_unstemmed Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate
title_short Aqua­bis(triphenyl­phosphine-κP)copper(I) tetra­fluoridoborate
title_sort aqua­bis(triphenyl­phosphine-κp)copper(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977191/
https://www.ncbi.nlm.nih.gov/pubmed/21583302
http://dx.doi.org/10.1107/S1600536809029559
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