Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate

The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic­ally independent [HgCl(2)(C(26)H(20)N(2))] mol­ecules and one acetonitrile solvent mol­ecule. The Hg(II) atoms are four-coordin­ated in distorted tetra­hedral configurations by two N atoms...

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Detalles Bibliográficos
Autores principales: Ahmadi, Roya, Kalateh, Khadijeh, Alizadeh, Robabeh, Khoshtarkib, Zeinab, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977193/
https://www.ncbi.nlm.nih.gov/pubmed/21583318
http://dx.doi.org/10.1107/S1600536809024180
Descripción
Sumario:The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic­ally independent [HgCl(2)(C(26)H(20)N(2))] mol­ecules and one acetonitrile solvent mol­ecule. The Hg(II) atoms are four-coordin­ated in distorted tetra­hedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61 (3) and 66.00 (3)° in the two molecules. In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distances = 3.809 (1), 3.686 (1), 3.986 (1), 3.877 (1), 3.697 (1), 3.789 (1), 3.745 (1), 3.797 (1) and 3.638 (1) Å] may stabilize the structure.

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