Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate

The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic­ally independent [HgCl(2)(C(26)H(20)N(2))] mol­ecules and one acetonitrile solvent mol­ecule. The Hg(II) atoms are four-coordin­ated in distorted tetra­hedral configurations by two N atoms...

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Autores principales: Ahmadi, Roya, Kalateh, Khadijeh, Alizadeh, Robabeh, Khoshtarkib, Zeinab, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977193/
https://www.ncbi.nlm.nih.gov/pubmed/21583318
http://dx.doi.org/10.1107/S1600536809024180
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author Ahmadi, Roya
Kalateh, Khadijeh
Alizadeh, Robabeh
Khoshtarkib, Zeinab
Amani, Vahid
author_facet Ahmadi, Roya
Kalateh, Khadijeh
Alizadeh, Robabeh
Khoshtarkib, Zeinab
Amani, Vahid
author_sort Ahmadi, Roya
collection PubMed
description The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic­ally independent [HgCl(2)(C(26)H(20)N(2))] mol­ecules and one acetonitrile solvent mol­ecule. The Hg(II) atoms are four-coordin­ated in distorted tetra­hedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61 (3) and 66.00 (3)° in the two molecules. In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distances = 3.809 (1), 3.686 (1), 3.986 (1), 3.877 (1), 3.697 (1), 3.789 (1), 3.745 (1), 3.797 (1) and 3.638 (1) Å] may stabilize the structure.
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spelling pubmed-29771932010-12-30 Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate Ahmadi, Roya Kalateh, Khadijeh Alizadeh, Robabeh Khoshtarkib, Zeinab Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic­ally independent [HgCl(2)(C(26)H(20)N(2))] mol­ecules and one acetonitrile solvent mol­ecule. The Hg(II) atoms are four-coordin­ated in distorted tetra­hedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring systems are not planar. The phenyl rings are oriented at dihedral angles of 74.61 (3) and 66.00 (3)° in the two molecules. In the crystal structure, π–π contacts between phenanthroline rings [centroid–centroid distances = 3.809 (1), 3.686 (1), 3.986 (1), 3.877 (1), 3.697 (1), 3.789 (1), 3.745 (1), 3.797 (1) and 3.638 (1) Å] may stabilize the structure. International Union of Crystallography 2009-07-01 /pmc/articles/PMC2977193/ /pubmed/21583318 http://dx.doi.org/10.1107/S1600536809024180 Text en © Ahmadi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ahmadi, Roya
Kalateh, Khadijeh
Alizadeh, Robabeh
Khoshtarkib, Zeinab
Amani, Vahid
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate
title Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate
title_full Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate
title_fullStr Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate
title_full_unstemmed Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate
title_short Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)mercury(II) acetonitrile hemisolvate
title_sort dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ(2) n,n′)mercury(ii) acetonitrile hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977193/
https://www.ncbi.nlm.nih.gov/pubmed/21583318
http://dx.doi.org/10.1107/S1600536809024180
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