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Aqua(1,10-phenanthroline-κ(2) N,N′)bis(trimethylacetato)-κ(2) O,O′;κO-cobalt(II)
In the title compound, [Co(C(5)H(9)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethylacetate ligands, one aqua O atom and two N atoms from 1,10-phenanthroline. The crystal structure is stabilized by O—H⋯O...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977194/ https://www.ncbi.nlm.nih.gov/pubmed/21583436 http://dx.doi.org/10.1107/S1600536809027251 |
| _version_ | 1782191049882468352 |
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| author | Chen, Xiao-Dan Chen, Hong-Xian Li, Zhong-Shu Zhang, Huai-Hong Sun, Bai-Wang |
| author_facet | Chen, Xiao-Dan Chen, Hong-Xian Li, Zhong-Shu Zhang, Huai-Hong Sun, Bai-Wang |
| author_sort | Chen, Xiao-Dan |
| collection | PubMed |
| description | In the title compound, [Co(C(5)H(9)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethylacetate ligands, one aqua O atom and two N atoms from 1,10-phenanthroline. The crystal structure is stabilized by O—H⋯O hydrogen bonds and π–π stacking interactions [interplanar distance between interdigitating 1,10-phenanthroline ligands = 3.378 (2) Å]. |
| format | Text |
| id | pubmed-2977194 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29771942010-12-30 Aqua(1,10-phenanthroline-κ(2) N,N′)bis(trimethylacetato)-κ(2) O,O′;κO-cobalt(II) Chen, Xiao-Dan Chen, Hong-Xian Li, Zhong-Shu Zhang, Huai-Hong Sun, Bai-Wang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(5)H(9)O(2))(2)(C(12)H(8)N(2))(H(2)O)], the Co(II) atom is coordinated in a distorted octahedral environment by three carboxyl O atoms of two trimethylacetate ligands, one aqua O atom and two N atoms from 1,10-phenanthroline. The crystal structure is stabilized by O—H⋯O hydrogen bonds and π–π stacking interactions [interplanar distance between interdigitating 1,10-phenanthroline ligands = 3.378 (2) Å]. International Union of Crystallography 2009-07-29 /pmc/articles/PMC2977194/ /pubmed/21583436 http://dx.doi.org/10.1107/S1600536809027251 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Xiao-Dan Chen, Hong-Xian Li, Zhong-Shu Zhang, Huai-Hong Sun, Bai-Wang Aqua(1,10-phenanthroline-κ(2) N,N′)bis(trimethylacetato)-κ(2) O,O′;κO-cobalt(II) |
| title | Aqua(1,10-phenanthroline-κ(2)
N,N′)bis(trimethylacetato)-κ(2)
O,O′;κO-cobalt(II) |
| title_full | Aqua(1,10-phenanthroline-κ(2)
N,N′)bis(trimethylacetato)-κ(2)
O,O′;κO-cobalt(II) |
| title_fullStr | Aqua(1,10-phenanthroline-κ(2)
N,N′)bis(trimethylacetato)-κ(2)
O,O′;κO-cobalt(II) |
| title_full_unstemmed | Aqua(1,10-phenanthroline-κ(2)
N,N′)bis(trimethylacetato)-κ(2)
O,O′;κO-cobalt(II) |
| title_short | Aqua(1,10-phenanthroline-κ(2)
N,N′)bis(trimethylacetato)-κ(2)
O,O′;κO-cobalt(II) |
| title_sort | aqua(1,10-phenanthroline-κ(2)
n,n′)bis(trimethylacetato)-κ(2)
o,o′;κo-cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977194/ https://www.ncbi.nlm.nih.gov/pubmed/21583436 http://dx.doi.org/10.1107/S1600536809027251 |
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