Cargando…

Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)

In the title compound, C(30)H(34)N(2)O(6), the complete molecule is generated by a crystallographic 2/m symmetry operation. The 1-oxyl-3-pyrroline-3-carboxyl­ate group lies on a mirror plane. The dihedral angle between the ring planes of the biphenyl fragment is constrained by symmetry to be zero, r...

Descripción completa

Detalles Bibliográficos
Autores principales: Margraf, Dominik, Schuetz, Denise, Prisner, Thomas F., Bats, Jan W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977196/
https://www.ncbi.nlm.nih.gov/pubmed/21583490
http://dx.doi.org/10.1107/S1600536809024659
_version_ 1782191050354327552
author Margraf, Dominik
Schuetz, Denise
Prisner, Thomas F.
Bats, Jan W.
author_facet Margraf, Dominik
Schuetz, Denise
Prisner, Thomas F.
Bats, Jan W.
author_sort Margraf, Dominik
collection PubMed
description In the title compound, C(30)H(34)N(2)O(6), the complete molecule is generated by a crystallographic 2/m symmetry operation. The 1-oxyl-3-pyrroline-3-carboxyl­ate group lies on a mirror plane. The dihedral angle between the ring planes of the biphenyl fragment is constrained by symmetry to be zero, resulting in rather short intramolecular H⋯H contact distances of 2.02 Å. In the crystal, molecules are connected along the a-axis direction by very weak intermolecular methyl–phenyl C—H⋯π interactions. The C—H bond is not directed to the center of the benzene ring, but mainly to one C atom [C—H⋯C(x − 1, y, z): H⋯C = 2.91 Å and C—H⋯C = 143°].
format Text
id pubmed-2977196
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29771962010-12-30 Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate) Margraf, Dominik Schuetz, Denise Prisner, Thomas F. Bats, Jan W. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(34)N(2)O(6), the complete molecule is generated by a crystallographic 2/m symmetry operation. The 1-oxyl-3-pyrroline-3-carboxyl­ate group lies on a mirror plane. The dihedral angle between the ring planes of the biphenyl fragment is constrained by symmetry to be zero, resulting in rather short intramolecular H⋯H contact distances of 2.02 Å. In the crystal, molecules are connected along the a-axis direction by very weak intermolecular methyl–phenyl C—H⋯π interactions. The C—H bond is not directed to the center of the benzene ring, but mainly to one C atom [C—H⋯C(x − 1, y, z): H⋯C = 2.91 Å and C—H⋯C = 143°]. International Union of Crystallography 2009-07-04 /pmc/articles/PMC2977196/ /pubmed/21583490 http://dx.doi.org/10.1107/S1600536809024659 Text en © Margraf et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Margraf, Dominik
Schuetz, Denise
Prisner, Thomas F.
Bats, Jan W.
Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
title Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
title_full Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
title_fullStr Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
title_full_unstemmed Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
title_short Biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
title_sort biphenyl-4,4′-diyl bis­(2,2,5,5-tetra­methyl-1-oxyl-3-pyrroline-3-carboxyl­ate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977196/
https://www.ncbi.nlm.nih.gov/pubmed/21583490
http://dx.doi.org/10.1107/S1600536809024659
work_keys_str_mv AT margrafdominik biphenyl44diylbis2255tetramethyl1oxyl3pyrroline3carboxylate
AT schuetzdenise biphenyl44diylbis2255tetramethyl1oxyl3pyrroline3carboxylate
AT prisnerthomasf biphenyl44diylbis2255tetramethyl1oxyl3pyrroline3carboxylate
AT batsjanw biphenyl44diylbis2255tetramethyl1oxyl3pyrroline3carboxylate