1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)

The title imidazolium-based ionic-liquid salt, C(18)H(24)N(4) (2+)·2PF(6) (−), has the cation lying about a center of inversion. The five-membered imidazole ring is disordered over two positions (the methyl substituents are ordered). This imidazole ring is approximately perpendicular to the six-memb...

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Detalles Bibliográficos
Autores principales: Puvaneswary, Subramaniam, Alias, Yatimah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977199/
https://www.ncbi.nlm.nih.gov/pubmed/21583532
http://dx.doi.org/10.1107/S1600536809026336
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author Puvaneswary, Subramaniam
Alias, Yatimah
Ng, Seik Weng
author_facet Puvaneswary, Subramaniam
Alias, Yatimah
Ng, Seik Weng
author_sort Puvaneswary, Subramaniam
collection PubMed
description The title imidazolium-based ionic-liquid salt, C(18)H(24)N(4) (2+)·2PF(6) (−), has the cation lying about a center of inversion. The five-membered imidazole ring is disordered over two positions (the methyl substituents are ordered). This imidazole ring is approximately perpendicular to the six-membered phenyl­ene ring [dihedral angle = 81.3 (8)° for one disorder component and 83.8 (8)° for the other; the two components are off-set by 2.7 (8)°]. The crystal is a non-merohedral twin with a twin component of 23%.
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spelling pubmed-29771992010-12-30 1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate) Puvaneswary, Subramaniam Alias, Yatimah Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title imidazolium-based ionic-liquid salt, C(18)H(24)N(4) (2+)·2PF(6) (−), has the cation lying about a center of inversion. The five-membered imidazole ring is disordered over two positions (the methyl substituents are ordered). This imidazole ring is approximately perpendicular to the six-membered phenyl­ene ring [dihedral angle = 81.3 (8)° for one disorder component and 83.8 (8)° for the other; the two components are off-set by 2.7 (8)°]. The crystal is a non-merohedral twin with a twin component of 23%. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977199/ /pubmed/21583532 http://dx.doi.org/10.1107/S1600536809026336 Text en © Puvaneswary et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Puvaneswary, Subramaniam
Alias, Yatimah
Ng, Seik Weng
1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
title 1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
title_full 1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
title_fullStr 1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
title_full_unstemmed 1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
title_short 1,1′,2,2′-Tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
title_sort 1,1′,2,2′-tetra­methyl-3,3′-(p-phenyl­enedimethyl­ene)diimidazol-1-ium bis­(hexa­fluoridophosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977199/
https://www.ncbi.nlm.nih.gov/pubmed/21583532
http://dx.doi.org/10.1107/S1600536809026336
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AT aliasyatimah 1122tetramethyl33pphenylenedimethylenediimidazol1iumbishexafluoridophosphate
AT ngseikweng 1122tetramethyl33pphenylenedimethylenediimidazol1iumbishexafluoridophosphate

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