1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea

The title compound, C(14)H(10)BrN(3)O(3)S, crystallizes as two concomitant polymorphs that differ in colour (one yellow and one colourless). Only the structure of the colourless form could be determined. The mol­ecule exists in the thio­amide form with an intra­molecular N—H⋯O=C hydrogen bond across...

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Detalles Bibliográficos
Autores principales: Saeed, Sohail, Rashid, Naghmana, Tahir, Arifa, Jones, Peter G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977201/
https://www.ncbi.nlm.nih.gov/pubmed/21583565
http://dx.doi.org/10.1107/S1600536809025884
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author Saeed, Sohail
Rashid, Naghmana
Tahir, Arifa
Jones, Peter G.
author_facet Saeed, Sohail
Rashid, Naghmana
Tahir, Arifa
Jones, Peter G.
author_sort Saeed, Sohail
collection PubMed
description The title compound, C(14)H(10)BrN(3)O(3)S, crystallizes as two concomitant polymorphs that differ in colour (one yellow and one colourless). Only the structure of the colourless form could be determined. The mol­ecule exists in the thio­amide form with an intra­molecular N—H⋯O=C hydrogen bond across the thio­urea system. Mol­ecules are linked into layers parallel to (120) by Br⋯O(nitro) contacts [3.103 (1) Å], classical hydrogen bonds from the other NH function to the S atom and N(nitro)⋯O=C contacts. The layers are linked by weak C—H⋯O(nitro) hydrogen bonds to produce the observed three-dimensional network.
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spelling pubmed-29772012010-12-30 1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea Saeed, Sohail Rashid, Naghmana Tahir, Arifa Jones, Peter G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(10)BrN(3)O(3)S, crystallizes as two concomitant polymorphs that differ in colour (one yellow and one colourless). Only the structure of the colourless form could be determined. The mol­ecule exists in the thio­amide form with an intra­molecular N—H⋯O=C hydrogen bond across the thio­urea system. Mol­ecules are linked into layers parallel to (120) by Br⋯O(nitro) contacts [3.103 (1) Å], classical hydrogen bonds from the other NH function to the S atom and N(nitro)⋯O=C contacts. The layers are linked by weak C—H⋯O(nitro) hydrogen bonds to produce the observed three-dimensional network. International Union of Crystallography 2009-07-15 /pmc/articles/PMC2977201/ /pubmed/21583565 http://dx.doi.org/10.1107/S1600536809025884 Text en © Saeed et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Sohail
Rashid, Naghmana
Tahir, Arifa
Jones, Peter G.
1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
title 1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
title_full 1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
title_fullStr 1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
title_full_unstemmed 1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
title_short 1-(4-Bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
title_sort 1-(4-bromo­phen­yl)-1-(4-nitro­benzo­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977201/
https://www.ncbi.nlm.nih.gov/pubmed/21583565
http://dx.doi.org/10.1107/S1600536809025884
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AT rashidnaghmana 14bromophenyl14nitrobenzoylthiourea
AT tahirarifa 14bromophenyl14nitrobenzoylthiourea
AT jonespeterg 14bromophenyl14nitrobenzoylthiourea

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