trans-Bis(2-benzoyl­benzoato-κO (1))bis­(ethanol-κO)bis­(1H-imidazole-κN (3))nickel(II)

In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(14)H(9)O(3))(2)(C(3)H(4)N(2))(2)(CH(3)CH(2)OH)(2)], the central Ni(II) ion lies on an inversion centre and is octa­hedrally coordinated. The equatorial plane is formed by two O atoms from two symmetry-related 2-benzoyl­benzoate ligan...

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Detalles Bibliográficos
Autores principales: Heren, Zerrin, Paşaoğlu, Hümeyra, Yıldırım, M. Hakkı, Hıra, Derya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977203/
https://www.ncbi.nlm.nih.gov/pubmed/21583367
http://dx.doi.org/10.1107/S160053680902621X
Descripción
Sumario:In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(14)H(9)O(3))(2)(C(3)H(4)N(2))(2)(CH(3)CH(2)OH)(2)], the central Ni(II) ion lies on an inversion centre and is octa­hedrally coordinated. The equatorial plane is formed by two O atoms from two symmetry-related 2-benzoyl­benzoate ligands and two N atoms from two symmetry-related imidazole ligands, whereas the axial positions are occupied by two O atoms from two ethanol ligands. Intramolecular O---H...O hydrogen bonds stabilize this arrangement. The mol­ecules are linked into chains running along the b axis by N—H⋯O hydrogen bonds.

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