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trans-Bis(2-benzoylbenzoato-κO (1))bis(ethanol-κO)bis(1H-imidazole-κN (3))nickel(II)
In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(14)H(9)O(3))(2)(C(3)H(4)N(2))(2)(CH(3)CH(2)OH)(2)], the central Ni(II) ion lies on an inversion centre and is octahedrally coordinated. The equatorial plane is formed by two O atoms from two symmetry-related 2-benzoylbenzoate ligan...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977203/ https://www.ncbi.nlm.nih.gov/pubmed/21583367 http://dx.doi.org/10.1107/S160053680902621X |
| _version_ | 1782191051980668928 |
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| author | Heren, Zerrin Paşaoğlu, Hümeyra Yıldırım, M. Hakkı Hıra, Derya |
| author_facet | Heren, Zerrin Paşaoğlu, Hümeyra Yıldırım, M. Hakkı Hıra, Derya |
| author_sort | Heren, Zerrin |
| collection | PubMed |
| description | In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(14)H(9)O(3))(2)(C(3)H(4)N(2))(2)(CH(3)CH(2)OH)(2)], the central Ni(II) ion lies on an inversion centre and is octahedrally coordinated. The equatorial plane is formed by two O atoms from two symmetry-related 2-benzoylbenzoate ligands and two N atoms from two symmetry-related imidazole ligands, whereas the axial positions are occupied by two O atoms from two ethanol ligands. Intramolecular O---H...O hydrogen bonds stabilize this arrangement. The molecules are linked into chains running along the b axis by N—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2977203 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29772032010-12-30 trans-Bis(2-benzoylbenzoato-κO (1))bis(ethanol-κO)bis(1H-imidazole-κN (3))nickel(II) Heren, Zerrin Paşaoğlu, Hümeyra Yıldırım, M. Hakkı Hıra, Derya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(14)H(9)O(3))(2)(C(3)H(4)N(2))(2)(CH(3)CH(2)OH)(2)], the central Ni(II) ion lies on an inversion centre and is octahedrally coordinated. The equatorial plane is formed by two O atoms from two symmetry-related 2-benzoylbenzoate ligands and two N atoms from two symmetry-related imidazole ligands, whereas the axial positions are occupied by two O atoms from two ethanol ligands. Intramolecular O---H...O hydrogen bonds stabilize this arrangement. The molecules are linked into chains running along the b axis by N—H⋯O hydrogen bonds. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977203/ /pubmed/21583367 http://dx.doi.org/10.1107/S160053680902621X Text en © Heren et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Heren, Zerrin Paşaoğlu, Hümeyra Yıldırım, M. Hakkı Hıra, Derya trans-Bis(2-benzoylbenzoato-κO (1))bis(ethanol-κO)bis(1H-imidazole-κN (3))nickel(II) |
| title |
trans-Bis(2-benzoylbenzoato-κO
(1))bis(ethanol-κO)bis(1H-imidazole-κN
(3))nickel(II) |
| title_full |
trans-Bis(2-benzoylbenzoato-κO
(1))bis(ethanol-κO)bis(1H-imidazole-κN
(3))nickel(II) |
| title_fullStr |
trans-Bis(2-benzoylbenzoato-κO
(1))bis(ethanol-κO)bis(1H-imidazole-κN
(3))nickel(II) |
| title_full_unstemmed |
trans-Bis(2-benzoylbenzoato-κO
(1))bis(ethanol-κO)bis(1H-imidazole-κN
(3))nickel(II) |
| title_short |
trans-Bis(2-benzoylbenzoato-κO
(1))bis(ethanol-κO)bis(1H-imidazole-κN
(3))nickel(II) |
| title_sort | trans-bis(2-benzoylbenzoato-κo
(1))bis(ethanol-κo)bis(1h-imidazole-κn
(3))nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977203/ https://www.ncbi.nlm.nih.gov/pubmed/21583367 http://dx.doi.org/10.1107/S160053680902621X |
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