catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]

The asymmetric unit of the title compound, {[Zn(2)(C(10)H(2)O(8))(H(2)O)(6)]·2H(2)O}(n), contains two distinct Zn atoms joined by a bridging water molecule and two bridging carboxyl­ate groups belonging to distinct halves of benzene-1,2,4,5-tetra­carboxyl­ate (tbec) tetra­anionic ligands, both lying...

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Detalles Bibliográficos
Autores principales: Rotondo, Archimede, Bruno, Giuseppe, Nicoló, Francesco, Cento, Angelo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977204/
https://www.ncbi.nlm.nih.gov/pubmed/21583373
http://dx.doi.org/10.1107/S160053680902666X
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author Rotondo, Archimede
Bruno, Giuseppe
Nicoló, Francesco
Cento, Angelo
author_facet Rotondo, Archimede
Bruno, Giuseppe
Nicoló, Francesco
Cento, Angelo
author_sort Rotondo, Archimede
collection PubMed
description The asymmetric unit of the title compound, {[Zn(2)(C(10)H(2)O(8))(H(2)O)(6)]·2H(2)O}(n), contains two distinct Zn atoms joined by a bridging water molecule and two bridging carboxyl­ate groups belonging to distinct halves of benzene-1,2,4,5-tetra­carboxyl­ate (tbec) tetra­anionic ligands, both lying on crystallographic inversion centres. The structure of this new isopolymorphic one-dimensional coordination polymer features asymmetric bimetallic octa­hedral knots. O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms help to consolidate the crystal packing.
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spelling pubmed-29772042010-12-30 catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate] Rotondo, Archimede Bruno, Giuseppe Nicoló, Francesco Cento, Angelo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Zn(2)(C(10)H(2)O(8))(H(2)O)(6)]·2H(2)O}(n), contains two distinct Zn atoms joined by a bridging water molecule and two bridging carboxyl­ate groups belonging to distinct halves of benzene-1,2,4,5-tetra­carboxyl­ate (tbec) tetra­anionic ligands, both lying on crystallographic inversion centres. The structure of this new isopolymorphic one-dimensional coordination polymer features asymmetric bimetallic octa­hedral knots. O—H⋯O hydrogen bonds between water molecules and carboxylate O atoms help to consolidate the crystal packing. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977204/ /pubmed/21583373 http://dx.doi.org/10.1107/S160053680902666X Text en © Rotondo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rotondo, Archimede
Bruno, Giuseppe
Nicoló, Francesco
Cento, Angelo
catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_full catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_fullStr catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_full_unstemmed catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_short catena-Poly[[[μ-aqua-penta­aqua­dizinc(II)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
title_sort catena-poly[[[μ-aqua-penta­aqua­dizinc(ii)]-μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977204/
https://www.ncbi.nlm.nih.gov/pubmed/21583373
http://dx.doi.org/10.1107/S160053680902666X
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AT nicolofrancesco catenapolymaquapentaaquadizinciim4benzene1245tetracarboxylatodihydrate
AT centoangelo catenapolymaquapentaaquadizinciim4benzene1245tetracarboxylatodihydrate

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